Reaction of alkyl- and arylamines with 2-(hydroxyimino)-3-oxobutanal

The condensation of 2-(hydroxyimino)-3-oxobutanal with primary aliphatic amines, cyclohexanamine, and amines containing an adamantane fragment afforded 4-(alkylamino)- and 4-(cyclohexylamino)-3- nitrosobut-3-en-2-ones. Analogous reaction with substituted anilines RC 6 H 4 NH 2 (R = H, 4-Me, 4-OMe, 4...

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Bibliographic Details
Published in:Russian journal of organic chemistry 2017, Vol.53 (1), p.1-5
Main Authors: Yarofeeva, A. A., Tsutsura, O. A., Frolenko, T. A., Semichenko, E. S., Kondrasenko, A. A., Suboch, G. A.
Format: Article
Language:English
Subjects:
Aliphatic amines
Amines
Aniline
Chemistry
Chemistry and Materials Science
Nitrogen dioxide
Organic Chemistry
Organic compounds
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Summary:The condensation of 2-(hydroxyimino)-3-oxobutanal with primary aliphatic amines, cyclohexanamine, and amines containing an adamantane fragment afforded 4-(alkylamino)- and 4-(cyclohexylamino)-3- nitrosobut-3-en-2-ones. Analogous reaction with substituted anilines RC 6 H 4 NH 2 (R = H, 4-Me, 4-OMe, 4-NH 2 , 4-Br, 4-I, 3-NO 2 ) led to the formation of 4-aryl-3-hydroxyiminobutan-2-ones.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428017010018