Loading…
Determination of 13C/12C Isotope Ratio in Alcohols of Different Origin by 1н Nuclei NMR-Spectroscopy
A new express method of indirect assessment of 13 C/ 12 C isotope ratio on 1 H nuclei is developed to verify the authenticity of ethanol origin in alcohol-water-based fluids and assess the facts of various alcoholic beverages falsification. It is established that in water-based alcohol-containing sy...
Saved in:
| Published in: | Russian physics journal 2017, Vol.59 (10), p.1710-1714 |
|---|---|
| Main Authors: | , , , , , , , |
| Format: | Article |
| Language: | English |
| Subjects: | |
| Citations: | Items that this one cites Items that cite this one |
| Online Access: | Get full text |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| cited_by | cdi_FETCH-LOGICAL-c1612-30b32b4f8ce7b9e167f81506a509710875cb721a5ba7fefde94cf1b96caead23 |
|---|---|
| cites | cdi_FETCH-LOGICAL-c1612-30b32b4f8ce7b9e167f81506a509710875cb721a5ba7fefde94cf1b96caead23 |
| container_end_page | 1714 |
| container_issue | 10 |
| container_start_page | 1710 |
| container_title | Russian physics journal |
| container_volume | 59 |
| creator | Dzhimak, S. S. Basov, A. A. Buzko, V. Yu Kopytov, G. F. Kashaev, D. V. Shashkov, D. I. Shlapakov, M. S. Baryshev, M. G. |
| description | A new express method of indirect assessment of
13
C/
12
C isotope ratio on
1
H nuclei is developed to verify the authenticity of ethanol origin in alcohol-water-based fluids and assess the facts of various alcoholic beverages falsification. It is established that in water-based alcohol-containing systems, side satellites for the signals of ethanol methyl and methylene protons in the NMR spectra on
1
H nuclei, correspond to the protons associated with
13
C nuclei. There is a direct correlation between the intensities of the signals of ethanol methyl and methylene protons’
1
H- NMR and their side satellites, therefore, the data obtained can be used to assess
13
C/
12
C isotope ratio in water-based alcohol-containing systems. The analysis of integrated intensities of main and satellite signals of methyl and methylene protons of ethanol obtained by NMR on
1
H nuclei makes it possible to differentiate between ethanol of synthetic and natural origin. Furthermore, the method proposed made it possible to differentiate between wheat and corn ethanol. |
| doi_str_mv | 10.1007/s11182-017-0965-2 |
| format | article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_1880759385</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1880759385</sourcerecordid><originalsourceid>FETCH-LOGICAL-c1612-30b32b4f8ce7b9e167f81506a509710875cb721a5ba7fefde94cf1b96caead23</originalsourceid><addsrcrecordid>eNp1kE1OwzAQhS0EEqVwAHaWWJt6nCZ2llXKT6XSSqV7K3HHJVUaBztd9HDcgSORKCzYsJqR3vfejB4h98AfgXM5CQCgBOMgGU-TmIkLMoJYRiwVQl12O0-mTCklr8lNCAfOO1ciRwTn2KI_lnXelq6mzlKIsgmIjC6Ca12DdNMrtKzprDLuw1Whh-alteixbunal_tOLM4Uvr_o6mQqLOnqbcPeGzStd8G45nxLrmxeBbz7nWOyfX7aZq9suX5ZZLMlM5CAYBEvIlFMrTIoixQhkVZBzJM85qkErmRsCikgj4tcWrQ7TKfGQpEmJsd8J6IxeRhiG-8-TxhafXAnX3cXNSjFZZxGKu4oGCjTfRc8Wt348pj7swau-zL1UKbuytR9mbpPFoMndGy9R_8n-V_TD_Vxdr0</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1880759385</pqid></control><display><type>article</type><title>Determination of 13C/12C Isotope Ratio in Alcohols of Different Origin by 1н Nuclei NMR-Spectroscopy</title><source>Springer Link</source><creator>Dzhimak, S. S. ; Basov, A. A. ; Buzko, V. Yu ; Kopytov, G. F. ; Kashaev, D. V. ; Shashkov, D. I. ; Shlapakov, M. S. ; Baryshev, M. G.</creator><creatorcontrib>Dzhimak, S. S. ; Basov, A. A. ; Buzko, V. Yu ; Kopytov, G. F. ; Kashaev, D. V. ; Shashkov, D. I. ; Shlapakov, M. S. ; Baryshev, M. G.</creatorcontrib><description>A new express method of indirect assessment of
13
C/
12
C isotope ratio on
1
H nuclei is developed to verify the authenticity of ethanol origin in alcohol-water-based fluids and assess the facts of various alcoholic beverages falsification. It is established that in water-based alcohol-containing systems, side satellites for the signals of ethanol methyl and methylene protons in the NMR spectra on
1
H nuclei, correspond to the protons associated with
13
C nuclei. There is a direct correlation between the intensities of the signals of ethanol methyl and methylene protons’
1
H- NMR and their side satellites, therefore, the data obtained can be used to assess
13
C/
12
C isotope ratio in water-based alcohol-containing systems. The analysis of integrated intensities of main and satellite signals of methyl and methylene protons of ethanol obtained by NMR on
1
H nuclei makes it possible to differentiate between ethanol of synthetic and natural origin. Furthermore, the method proposed made it possible to differentiate between wheat and corn ethanol.</description><identifier>ISSN: 1064-8887</identifier><identifier>EISSN: 1573-9228</identifier><identifier>DOI: 10.1007/s11182-017-0965-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Alcohol ; Alcoholic beverages ; Carbon 12 ; Condensed Matter Physics ; Ethanol ; Hadrons ; Heavy Ions ; Isotope ratios ; Isotopes ; Lasers ; Mathematical and Computational Physics ; Methylene ; NMR ; Nuclear magnetic resonance ; Nuclear Physics ; Nuclei ; Optical Devices ; Optics ; Photonics ; Physics ; Physics and Astronomy ; Physics of Magnetic Phenomena ; Protons ; Satellites ; Spectrum analysis ; Theoretical</subject><ispartof>Russian physics journal, 2017, Vol.59 (10), p.1710-1714</ispartof><rights>Springer Science+Business Media New York 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c1612-30b32b4f8ce7b9e167f81506a509710875cb721a5ba7fefde94cf1b96caead23</citedby><cites>FETCH-LOGICAL-c1612-30b32b4f8ce7b9e167f81506a509710875cb721a5ba7fefde94cf1b96caead23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,777,781,27905,27906</link.rule.ids></links><search><creatorcontrib>Dzhimak, S. S.</creatorcontrib><creatorcontrib>Basov, A. A.</creatorcontrib><creatorcontrib>Buzko, V. Yu</creatorcontrib><creatorcontrib>Kopytov, G. F.</creatorcontrib><creatorcontrib>Kashaev, D. V.</creatorcontrib><creatorcontrib>Shashkov, D. I.</creatorcontrib><creatorcontrib>Shlapakov, M. S.</creatorcontrib><creatorcontrib>Baryshev, M. G.</creatorcontrib><title>Determination of 13C/12C Isotope Ratio in Alcohols of Different Origin by 1н Nuclei NMR-Spectroscopy</title><title>Russian physics journal</title><addtitle>Russ Phys J</addtitle><description>A new express method of indirect assessment of
13
C/
12
C isotope ratio on
1
H nuclei is developed to verify the authenticity of ethanol origin in alcohol-water-based fluids and assess the facts of various alcoholic beverages falsification. It is established that in water-based alcohol-containing systems, side satellites for the signals of ethanol methyl and methylene protons in the NMR spectra on
1
H nuclei, correspond to the protons associated with
13
C nuclei. There is a direct correlation between the intensities of the signals of ethanol methyl and methylene protons’
1
H- NMR and their side satellites, therefore, the data obtained can be used to assess
13
C/
12
C isotope ratio in water-based alcohol-containing systems. The analysis of integrated intensities of main and satellite signals of methyl and methylene protons of ethanol obtained by NMR on
1
H nuclei makes it possible to differentiate between ethanol of synthetic and natural origin. Furthermore, the method proposed made it possible to differentiate between wheat and corn ethanol.</description><subject>Alcohol</subject><subject>Alcoholic beverages</subject><subject>Carbon 12</subject><subject>Condensed Matter Physics</subject><subject>Ethanol</subject><subject>Hadrons</subject><subject>Heavy Ions</subject><subject>Isotope ratios</subject><subject>Isotopes</subject><subject>Lasers</subject><subject>Mathematical and Computational Physics</subject><subject>Methylene</subject><subject>NMR</subject><subject>Nuclear magnetic resonance</subject><subject>Nuclear Physics</subject><subject>Nuclei</subject><subject>Optical Devices</subject><subject>Optics</subject><subject>Photonics</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Physics of Magnetic Phenomena</subject><subject>Protons</subject><subject>Satellites</subject><subject>Spectrum analysis</subject><subject>Theoretical</subject><issn>1064-8887</issn><issn>1573-9228</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kE1OwzAQhS0EEqVwAHaWWJt6nCZ2llXKT6XSSqV7K3HHJVUaBztd9HDcgSORKCzYsJqR3vfejB4h98AfgXM5CQCgBOMgGU-TmIkLMoJYRiwVQl12O0-mTCklr8lNCAfOO1ciRwTn2KI_lnXelq6mzlKIsgmIjC6Ca12DdNMrtKzprDLuw1Whh-alteixbunal_tOLM4Uvr_o6mQqLOnqbcPeGzStd8G45nxLrmxeBbz7nWOyfX7aZq9suX5ZZLMlM5CAYBEvIlFMrTIoixQhkVZBzJM85qkErmRsCikgj4tcWrQ7TKfGQpEmJsd8J6IxeRhiG-8-TxhafXAnX3cXNSjFZZxGKu4oGCjTfRc8Wt348pj7swau-zL1UKbuytR9mbpPFoMndGy9R_8n-V_TD_Vxdr0</recordid><startdate>2017</startdate><enddate>2017</enddate><creator>Dzhimak, S. S.</creator><creator>Basov, A. A.</creator><creator>Buzko, V. Yu</creator><creator>Kopytov, G. F.</creator><creator>Kashaev, D. V.</creator><creator>Shashkov, D. I.</creator><creator>Shlapakov, M. S.</creator><creator>Baryshev, M. G.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2017</creationdate><title>Determination of 13C/12C Isotope Ratio in Alcohols of Different Origin by 1н Nuclei NMR-Spectroscopy</title><author>Dzhimak, S. S. ; Basov, A. A. ; Buzko, V. Yu ; Kopytov, G. F. ; Kashaev, D. V. ; Shashkov, D. I. ; Shlapakov, M. S. ; Baryshev, M. G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c1612-30b32b4f8ce7b9e167f81506a509710875cb721a5ba7fefde94cf1b96caead23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Alcohol</topic><topic>Alcoholic beverages</topic><topic>Carbon 12</topic><topic>Condensed Matter Physics</topic><topic>Ethanol</topic><topic>Hadrons</topic><topic>Heavy Ions</topic><topic>Isotope ratios</topic><topic>Isotopes</topic><topic>Lasers</topic><topic>Mathematical and Computational Physics</topic><topic>Methylene</topic><topic>NMR</topic><topic>Nuclear magnetic resonance</topic><topic>Nuclear Physics</topic><topic>Nuclei</topic><topic>Optical Devices</topic><topic>Optics</topic><topic>Photonics</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Physics of Magnetic Phenomena</topic><topic>Protons</topic><topic>Satellites</topic><topic>Spectrum analysis</topic><topic>Theoretical</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Dzhimak, S. S.</creatorcontrib><creatorcontrib>Basov, A. A.</creatorcontrib><creatorcontrib>Buzko, V. Yu</creatorcontrib><creatorcontrib>Kopytov, G. F.</creatorcontrib><creatorcontrib>Kashaev, D. V.</creatorcontrib><creatorcontrib>Shashkov, D. I.</creatorcontrib><creatorcontrib>Shlapakov, M. S.</creatorcontrib><creatorcontrib>Baryshev, M. G.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian physics journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Dzhimak, S. S.</au><au>Basov, A. A.</au><au>Buzko, V. Yu</au><au>Kopytov, G. F.</au><au>Kashaev, D. V.</au><au>Shashkov, D. I.</au><au>Shlapakov, M. S.</au><au>Baryshev, M. G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of 13C/12C Isotope Ratio in Alcohols of Different Origin by 1н Nuclei NMR-Spectroscopy</atitle><jtitle>Russian physics journal</jtitle><stitle>Russ Phys J</stitle><date>2017</date><risdate>2017</risdate><volume>59</volume><issue>10</issue><spage>1710</spage><epage>1714</epage><pages>1710-1714</pages><issn>1064-8887</issn><eissn>1573-9228</eissn><abstract>A new express method of indirect assessment of
13
C/
12
C isotope ratio on
1
H nuclei is developed to verify the authenticity of ethanol origin in alcohol-water-based fluids and assess the facts of various alcoholic beverages falsification. It is established that in water-based alcohol-containing systems, side satellites for the signals of ethanol methyl and methylene protons in the NMR spectra on
1
H nuclei, correspond to the protons associated with
13
C nuclei. There is a direct correlation between the intensities of the signals of ethanol methyl and methylene protons’
1
H- NMR and their side satellites, therefore, the data obtained can be used to assess
13
C/
12
C isotope ratio in water-based alcohol-containing systems. The analysis of integrated intensities of main and satellite signals of methyl and methylene protons of ethanol obtained by NMR on
1
H nuclei makes it possible to differentiate between ethanol of synthetic and natural origin. Furthermore, the method proposed made it possible to differentiate between wheat and corn ethanol.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11182-017-0965-2</doi><tpages>5</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1064-8887 |
| ispartof | Russian physics journal, 2017, Vol.59 (10), p.1710-1714 |
| issn | 1064-8887 1573-9228 |
| language | eng |
| recordid | cdi_proquest_journals_1880759385 |
| source | Springer Link |
| subjects | Alcohol Alcoholic beverages Carbon 12 Condensed Matter Physics Ethanol Hadrons Heavy Ions Isotope ratios Isotopes Lasers Mathematical and Computational Physics Methylene NMR Nuclear magnetic resonance Nuclear Physics Nuclei Optical Devices Optics Photonics Physics Physics and Astronomy Physics of Magnetic Phenomena Protons Satellites Spectrum analysis Theoretical |
| title | Determination of 13C/12C Isotope Ratio in Alcohols of Different Origin by 1н Nuclei NMR-Spectroscopy |
| url | http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-19T09%3A12%3A48IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Determination%20of%2013C/12C%20Isotope%20Ratio%20in%20Alcohols%20of%20Different%20Origin%20by%201%D0%BD%20Nuclei%20NMR-Spectroscopy&rft.jtitle=Russian%20physics%20journal&rft.au=Dzhimak,%20S.%20S.&rft.date=2017&rft.volume=59&rft.issue=10&rft.spage=1710&rft.epage=1714&rft.pages=1710-1714&rft.issn=1064-8887&rft.eissn=1573-9228&rft_id=info:doi/10.1007/s11182-017-0965-2&rft_dat=%3Cproquest_cross%3E1880759385%3C/proquest_cross%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c1612-30b32b4f8ce7b9e167f81506a509710875cb721a5ba7fefde94cf1b96caead23%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1880759385&rft_id=info:pmid/&rfr_iscdi=true |