Synthesis of manganese dioxide by homogeneous hydrolysis in the presence of melamine

A new selective method for the synthesis of nanocrystalline manganese dioxide (α-, β-, and γ-MnO 2 ) based on the reaction of potassium permanganate with 2,4,6-triamino-1,3,5-triazine (melamine) under hydrothermal conditions has been proposed. Effect of synthesis conditions on the phase composition...

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Bibliographic Details
Published in:Russian journal of inorganic chemistry 2017-02, Vol.62 (2), p.139-149
Main Authors: Sharipov, Kh. B., Yapryntsev, A. D., Baranchikov, A. E., Boytsova, O. V., Kurzeev, S. A., Ivanova, O. S., Borilo, L. P., Gil’mutdinov, F. Z., Kozik, V. V., Ivanov, V. K.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Composition effects
Inorganic Chemistry
Manganese dioxide
Melamine
Phase composition
Potassium permanganate
Synthesis
Synthesis and Properties of Inorganic Compounds
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Summary:A new selective method for the synthesis of nanocrystalline manganese dioxide (α-, β-, and γ-MnO 2 ) based on the reaction of potassium permanganate with 2,4,6-triamino-1,3,5-triazine (melamine) under hydrothermal conditions has been proposed. Effect of synthesis conditions on the phase composition of the products has been revealed. A new manganese-containing phase with layered structure has been prepared.
ISSN:0036-0236
1531-8613
DOI:10.1134/S0036023617020164