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Luminescent Sensing of Volatile Organic Compounds Using a Zn-based Coordination Polymer with Tunable Morphology
Here we report the mechanochemical synthesis of Zn(ADB) n coordination polymer (ADB: azobenzene 4, 4′-dicarboxilic acid) in good yield, which provides advanced over conventional route as it is simple, faster, cost-effective and reproducible. Both coordination polymers were characterized by X-ray pow...
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| Published in: | Journal of inorganic and organometallic polymers and materials 2017-03, Vol.27 (2), p.467-473 |
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| Main Authors: | , , , , , , |
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| Language: | English |
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| container_end_page | 473 |
| container_issue | 2 |
| container_start_page | 467 |
| container_title | Journal of inorganic and organometallic polymers and materials |
| container_volume | 27 |
| creator | Chan-Navarro, Rodrigo Corpus-Coronado, Dante Muñoz-Flores, Blanca M. Loredo-Cancino, Margarita Waksman, Noemí Ramírez, Rosalba Jiménez-Pérez, Víctor M. |
| description | Here we report the mechanochemical synthesis of Zn(ADB)
n
coordination polymer (ADB: azobenzene 4, 4′-dicarboxilic acid) in good yield, which provides advanced over conventional route as it is simple, faster, cost-effective and reproducible. Both coordination polymers were characterized by X-ray powder diffraction (PXRD), field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, and simultaneous thermal analysis. PXRD studies showed that both materials exhibited the same pattern, proving the presence of the crystalline coordination polymer core. FESEM micrograph images showed plate shape microstructures with a length of 10 µm, and a thickness in range from 14 to 21 µm, which suggested that synthetic routes affect the coordination polymer morphology. The resulting coordination polymers have low porosity with surface areas around from 1.92 to 1.25 m
2
g
− 1
and pore sizes in range from 0.36 to 0.61 nm for mechanochemical and room temperature stirring routes, respectively. In a preliminary fluorescent sensing study, the coordination polymer soaked with different volatile organic compounds showed noticeable shifts of the emission band in comparison with the same materials free solvent.
Graphical Abstract |
| doi_str_mv | 10.1007/s10904-016-0488-2 |
| format | article |
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n
coordination polymer (ADB: azobenzene 4, 4′-dicarboxilic acid) in good yield, which provides advanced over conventional route as it is simple, faster, cost-effective and reproducible. Both coordination polymers were characterized by X-ray powder diffraction (PXRD), field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, and simultaneous thermal analysis. PXRD studies showed that both materials exhibited the same pattern, proving the presence of the crystalline coordination polymer core. FESEM micrograph images showed plate shape microstructures with a length of 10 µm, and a thickness in range from 14 to 21 µm, which suggested that synthetic routes affect the coordination polymer morphology. The resulting coordination polymers have low porosity with surface areas around from 1.92 to 1.25 m
2
g
− 1
and pore sizes in range from 0.36 to 0.61 nm for mechanochemical and room temperature stirring routes, respectively. In a preliminary fluorescent sensing study, the coordination polymer soaked with different volatile organic compounds showed noticeable shifts of the emission band in comparison with the same materials free solvent.
Graphical Abstract</description><identifier>ISSN: 1574-1443</identifier><identifier>EISSN: 1574-1451</identifier><identifier>DOI: 10.1007/s10904-016-0488-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Azo compounds ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Coordination polymers ; Diffraction patterns ; Field emission microscopy ; Field emission spectroscopy ; Fluorescence ; Inorganic Chemistry ; Morphology ; Organic Chemistry ; Pattern analysis ; Photomicrographs ; Polymer Sciences ; Polymers ; Room temperature ; Thermal analysis ; Thickness ; VOCs ; Volatile organic compounds ; X ray powder diffraction ; Zinc compounds</subject><ispartof>Journal of inorganic and organometallic polymers and materials, 2017-03, Vol.27 (2), p.467-473</ispartof><rights>Springer Science+Business Media New York 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-92e7779cf4a34a21126567327e7a4ff06b7fc274db3c945d2596a667625088a43</citedby><cites>FETCH-LOGICAL-c353t-92e7779cf4a34a21126567327e7a4ff06b7fc274db3c945d2596a667625088a43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Chan-Navarro, Rodrigo</creatorcontrib><creatorcontrib>Corpus-Coronado, Dante</creatorcontrib><creatorcontrib>Muñoz-Flores, Blanca M.</creatorcontrib><creatorcontrib>Loredo-Cancino, Margarita</creatorcontrib><creatorcontrib>Waksman, Noemí</creatorcontrib><creatorcontrib>Ramírez, Rosalba</creatorcontrib><creatorcontrib>Jiménez-Pérez, Víctor M.</creatorcontrib><title>Luminescent Sensing of Volatile Organic Compounds Using a Zn-based Coordination Polymer with Tunable Morphology</title><title>Journal of inorganic and organometallic polymers and materials</title><addtitle>J Inorg Organomet Polym</addtitle><description>Here we report the mechanochemical synthesis of Zn(ADB)
n
coordination polymer (ADB: azobenzene 4, 4′-dicarboxilic acid) in good yield, which provides advanced over conventional route as it is simple, faster, cost-effective and reproducible. Both coordination polymers were characterized by X-ray powder diffraction (PXRD), field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, and simultaneous thermal analysis. PXRD studies showed that both materials exhibited the same pattern, proving the presence of the crystalline coordination polymer core. FESEM micrograph images showed plate shape microstructures with a length of 10 µm, and a thickness in range from 14 to 21 µm, which suggested that synthetic routes affect the coordination polymer morphology. The resulting coordination polymers have low porosity with surface areas around from 1.92 to 1.25 m
2
g
− 1
and pore sizes in range from 0.36 to 0.61 nm for mechanochemical and room temperature stirring routes, respectively. In a preliminary fluorescent sensing study, the coordination polymer soaked with different volatile organic compounds showed noticeable shifts of the emission band in comparison with the same materials free solvent.
Graphical Abstract</description><subject>Azo compounds</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination polymers</subject><subject>Diffraction patterns</subject><subject>Field emission microscopy</subject><subject>Field emission spectroscopy</subject><subject>Fluorescence</subject><subject>Inorganic Chemistry</subject><subject>Morphology</subject><subject>Organic Chemistry</subject><subject>Pattern analysis</subject><subject>Photomicrographs</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Room temperature</subject><subject>Thermal analysis</subject><subject>Thickness</subject><subject>VOCs</subject><subject>Volatile organic compounds</subject><subject>X ray powder diffraction</subject><subject>Zinc compounds</subject><issn>1574-1443</issn><issn>1574-1451</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kE1LxDAURYMoOI7-AHcB19F8p13K4BeMjOCMCzchbdNOhzapSYvMv7djRdy4eg_euffBAeCS4GuCsbqJBKeYI0wkwjxJED0CMyIUR4QLcvy7c3YKzmLcYcwSLMgM-OXQ1s7G3LoevloXa1dBX8I335i-bixchcq4OocL33Z-cEWEm2_GwHeHMhNtMZ58KGo38t7BF9_sWxvgZ91v4XpwJhtLnn3otr7x1f4cnJSmifbiZ87B5v5uvXhEy9XD0-J2iXImWI9SapVSaV5yw7ihhFAppGJUWWV4WWKZqTKnihcZy1MuCipSaaRUkgqcJIazObiaervgPwYbe73zQ3DjS02SBCspmFIjRSYqDz7GYEvdhbo1Ya8J1gevevKqR6_64FXTMUOnTBxZV9nwp_nf0Bcg2Xrf</recordid><startdate>20170301</startdate><enddate>20170301</enddate><creator>Chan-Navarro, Rodrigo</creator><creator>Corpus-Coronado, Dante</creator><creator>Muñoz-Flores, Blanca M.</creator><creator>Loredo-Cancino, Margarita</creator><creator>Waksman, Noemí</creator><creator>Ramírez, Rosalba</creator><creator>Jiménez-Pérez, Víctor M.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170301</creationdate><title>Luminescent Sensing of Volatile Organic Compounds Using a Zn-based Coordination Polymer with Tunable Morphology</title><author>Chan-Navarro, Rodrigo ; Corpus-Coronado, Dante ; Muñoz-Flores, Blanca M. ; Loredo-Cancino, Margarita ; Waksman, Noemí ; Ramírez, Rosalba ; Jiménez-Pérez, Víctor M.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-92e7779cf4a34a21126567327e7a4ff06b7fc274db3c945d2596a667625088a43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Azo compounds</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination polymers</topic><topic>Diffraction patterns</topic><topic>Field emission microscopy</topic><topic>Field emission spectroscopy</topic><topic>Fluorescence</topic><topic>Inorganic Chemistry</topic><topic>Morphology</topic><topic>Organic Chemistry</topic><topic>Pattern analysis</topic><topic>Photomicrographs</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Room temperature</topic><topic>Thermal analysis</topic><topic>Thickness</topic><topic>VOCs</topic><topic>Volatile organic compounds</topic><topic>X ray powder diffraction</topic><topic>Zinc compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Chan-Navarro, Rodrigo</creatorcontrib><creatorcontrib>Corpus-Coronado, Dante</creatorcontrib><creatorcontrib>Muñoz-Flores, Blanca M.</creatorcontrib><creatorcontrib>Loredo-Cancino, Margarita</creatorcontrib><creatorcontrib>Waksman, Noemí</creatorcontrib><creatorcontrib>Ramírez, Rosalba</creatorcontrib><creatorcontrib>Jiménez-Pérez, Víctor M.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Chan-Navarro, Rodrigo</au><au>Corpus-Coronado, Dante</au><au>Muñoz-Flores, Blanca M.</au><au>Loredo-Cancino, Margarita</au><au>Waksman, Noemí</au><au>Ramírez, Rosalba</au><au>Jiménez-Pérez, Víctor M.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Luminescent Sensing of Volatile Organic Compounds Using a Zn-based Coordination Polymer with Tunable Morphology</atitle><jtitle>Journal of inorganic and organometallic polymers and materials</jtitle><stitle>J Inorg Organomet Polym</stitle><date>2017-03-01</date><risdate>2017</risdate><volume>27</volume><issue>2</issue><spage>467</spage><epage>473</epage><pages>467-473</pages><issn>1574-1443</issn><eissn>1574-1451</eissn><abstract>Here we report the mechanochemical synthesis of Zn(ADB)
n
coordination polymer (ADB: azobenzene 4, 4′-dicarboxilic acid) in good yield, which provides advanced over conventional route as it is simple, faster, cost-effective and reproducible. Both coordination polymers were characterized by X-ray powder diffraction (PXRD), field emission scanning electron microscopy, energy dispersive X-ray spectroscopy, and simultaneous thermal analysis. PXRD studies showed that both materials exhibited the same pattern, proving the presence of the crystalline coordination polymer core. FESEM micrograph images showed plate shape microstructures with a length of 10 µm, and a thickness in range from 14 to 21 µm, which suggested that synthetic routes affect the coordination polymer morphology. The resulting coordination polymers have low porosity with surface areas around from 1.92 to 1.25 m
2
g
− 1
and pore sizes in range from 0.36 to 0.61 nm for mechanochemical and room temperature stirring routes, respectively. In a preliminary fluorescent sensing study, the coordination polymer soaked with different volatile organic compounds showed noticeable shifts of the emission band in comparison with the same materials free solvent.
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| subjects | Azo compounds Chemical synthesis Chemistry Chemistry and Materials Science Coordination polymers Diffraction patterns Field emission microscopy Field emission spectroscopy Fluorescence Inorganic Chemistry Morphology Organic Chemistry Pattern analysis Photomicrographs Polymer Sciences Polymers Room temperature Thermal analysis Thickness VOCs Volatile organic compounds X ray powder diffraction Zinc compounds |
| title | Luminescent Sensing of Volatile Organic Compounds Using a Zn-based Coordination Polymer with Tunable Morphology |
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