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Use of amberlite XAD-7HP for the separation of Mn(II) and Mn(VII) in waters
A simple method is proposed for the determination and speciation of Mn(II) and Mn(VII) in waters utilizing a macroporous resin, Amberlite XAD-7HP. The batch method was employed and flame atomic absorption spectrometry was used in all determinations. Amberlite XAD-7HP resin was shown to retain Mn(VII...
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Published in: | Journal of analytical chemistry (New York, N.Y.) N.Y.), 2017, Vol.72 (1), p.63-69 |
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container_title | Journal of analytical chemistry (New York, N.Y.) |
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creator | Yayayürük, Aslı Erdem Eroğlub, Ahmet E. |
description | A simple method is proposed for the determination and speciation of Mn(II) and Mn(VII) in waters utilizing a macroporous resin, Amberlite XAD-7HP. The batch method was employed and flame atomic absorption spectrometry was used in all determinations. Amberlite XAD-7HP resin was shown to retain Mn(VII) between pH 4 and 12. If the solution contains only one of the species, either Mn(II) or Mn(VII), the resin behaves selectively depending on the pH of the solution. The elution from the sorbent was realized using K
2
C
2
O
4
in HNO
3
. The efficiency of the method was checked via spike recovery experiments. The proposed method was successfully applied to industrial wastewater samples and quantitative recoveries (≥96.0%) confirmed the accuracy of the method. |
doi_str_mv | 10.1134/S106193481701004X |
format | article |
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2
C
2
O
4
in HNO
3
. The efficiency of the method was checked via spike recovery experiments. The proposed method was successfully applied to industrial wastewater samples and quantitative recoveries (≥96.0%) confirmed the accuracy of the method.</description><identifier>ISSN: 1061-9348</identifier><identifier>EISSN: 1608-3199</identifier><identifier>DOI: 10.1134/S106193481701004X</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Absorption spectroscopy ; Amberlite (trademark) ; Analytical Chemistry ; Atomic absorption analysis ; Chemistry ; Chemistry and Materials Science ; Elution ; Industrial wastes ; Speciation ; Spectrometry ; Wastewater</subject><ispartof>Journal of analytical chemistry (New York, N.Y.), 2017, Vol.72 (1), p.63-69</ispartof><rights>Pleiades Publishing, Ltd. 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c359t-88762aea04f9991e3c576e4d622a3418ccc81e53fa6a864cf5da0b44ebf699d73</citedby><cites>FETCH-LOGICAL-c359t-88762aea04f9991e3c576e4d622a3418ccc81e53fa6a864cf5da0b44ebf699d73</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Yayayürük, Aslı Erdem</creatorcontrib><creatorcontrib>Eroğlub, Ahmet E.</creatorcontrib><title>Use of amberlite XAD-7HP for the separation of Mn(II) and Mn(VII) in waters</title><title>Journal of analytical chemistry (New York, N.Y.)</title><addtitle>J Anal Chem</addtitle><description>A simple method is proposed for the determination and speciation of Mn(II) and Mn(VII) in waters utilizing a macroporous resin, Amberlite XAD-7HP. The batch method was employed and flame atomic absorption spectrometry was used in all determinations. Amberlite XAD-7HP resin was shown to retain Mn(VII) between pH 4 and 12. If the solution contains only one of the species, either Mn(II) or Mn(VII), the resin behaves selectively depending on the pH of the solution. The elution from the sorbent was realized using K
2
C
2
O
4
in HNO
3
. The efficiency of the method was checked via spike recovery experiments. The proposed method was successfully applied to industrial wastewater samples and quantitative recoveries (≥96.0%) confirmed the accuracy of the method.</description><subject>Absorption spectroscopy</subject><subject>Amberlite (trademark)</subject><subject>Analytical Chemistry</subject><subject>Atomic absorption analysis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Elution</subject><subject>Industrial wastes</subject><subject>Speciation</subject><subject>Spectrometry</subject><subject>Wastewater</subject><issn>1061-9348</issn><issn>1608-3199</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLw0AUhQdRsFZ_gLsBN7qIzs1M5rEs9dFgRUEr3YXp5I6mtEmdSRH_vQl1IYire-B851w4hJwCuwTg4uoZmATDhQbFgDEx3yMDkEwnHIzZ73RnJ71_SI5iXDLGjAY5IPeziLTx1K4XGFZVi3Q-uk7U5In6JtD2HWnEjQ22rZq65x7q8zy_oLYue_na66qmn7bFEI_JgberiCc_d0hmtzcv40kyfbzLx6Np4nhm2kRrJVOLlglvjAHkLlMSRSnT1HIB2jmnATPurbRaCuez0rKFELjw0phS8SE52_VuQvOxxdgWy2Yb6u5lAVozJVWqs46CHeVCE2NAX2xCtbbhqwBW9JsVfzbrMukuEzu2fsPwq_nf0DfSWmqX</recordid><startdate>2017</startdate><enddate>2017</enddate><creator>Yayayürük, Aslı Erdem</creator><creator>Eroğlub, Ahmet E.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2017</creationdate><title>Use of amberlite XAD-7HP for the separation of Mn(II) and Mn(VII) in waters</title><author>Yayayürük, Aslı Erdem ; Eroğlub, Ahmet E.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c359t-88762aea04f9991e3c576e4d622a3418ccc81e53fa6a864cf5da0b44ebf699d73</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Absorption spectroscopy</topic><topic>Amberlite (trademark)</topic><topic>Analytical Chemistry</topic><topic>Atomic absorption analysis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Elution</topic><topic>Industrial wastes</topic><topic>Speciation</topic><topic>Spectrometry</topic><topic>Wastewater</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yayayürük, Aslı Erdem</creatorcontrib><creatorcontrib>Eroğlub, Ahmet E.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yayayürük, Aslı Erdem</au><au>Eroğlub, Ahmet E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Use of amberlite XAD-7HP for the separation of Mn(II) and Mn(VII) in waters</atitle><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle><stitle>J Anal Chem</stitle><date>2017</date><risdate>2017</risdate><volume>72</volume><issue>1</issue><spage>63</spage><epage>69</epage><pages>63-69</pages><issn>1061-9348</issn><eissn>1608-3199</eissn><abstract>A simple method is proposed for the determination and speciation of Mn(II) and Mn(VII) in waters utilizing a macroporous resin, Amberlite XAD-7HP. The batch method was employed and flame atomic absorption spectrometry was used in all determinations. Amberlite XAD-7HP resin was shown to retain Mn(VII) between pH 4 and 12. If the solution contains only one of the species, either Mn(II) or Mn(VII), the resin behaves selectively depending on the pH of the solution. The elution from the sorbent was realized using K
2
C
2
O
4
in HNO
3
. The efficiency of the method was checked via spike recovery experiments. The proposed method was successfully applied to industrial wastewater samples and quantitative recoveries (≥96.0%) confirmed the accuracy of the method.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S106193481701004X</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
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source | Springer Nature |
subjects | Absorption spectroscopy Amberlite (trademark) Analytical Chemistry Atomic absorption analysis Chemistry Chemistry and Materials Science Elution Industrial wastes Speciation Spectrometry Wastewater |
title | Use of amberlite XAD-7HP for the separation of Mn(II) and Mn(VII) in waters |
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