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Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II)
The structure of the dimeric complex [Co 2 (BuOH) 4 (Detba) 4 ] ( I ), where НDetba is 1,3-diethyl-2-thiobarbituric acid, and BuOH is butanol-1, is determined (CIF file CCDC 1475273), and its IR spectrum is studied. The crystals are monoclinic: a = 10.7185(5), b = 21.985(1), c = 12.7235(7) Å, β = 92...
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| Published in: | Russian journal of coordination chemistry 2017-02, Vol.43 (2), p.82-85 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c316t-10b3b6fd45a634884cdf9a7fcd608ee4a81975fbcb231f9239c58856604a867d3 |
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| cites | cdi_FETCH-LOGICAL-c316t-10b3b6fd45a634884cdf9a7fcd608ee4a81975fbcb231f9239c58856604a867d3 |
| container_end_page | 85 |
| container_issue | 2 |
| container_start_page | 82 |
| container_title | Russian journal of coordination chemistry |
| container_volume | 43 |
| creator | Golovnev, N. N. Molokeev, M. S. Smolentsev, A. I. Lesnikov, M. K. |
| description | The structure of the dimeric complex [Co
2
(BuOH)
4
(Detba)
4
] (
I
), where НDetba is 1,3-diethyl-2-thiobarbituric acid, and BuOH is butanol-1, is determined (CIF file CCDC 1475273), and its IR spectrum is studied. The crystals are monoclinic:
a
= 10.7185(5),
b
= 21.985(1),
c
= 12.7235(7) Å, β = 92.196(2)°,
V
= 2996.1(3) Å
3
, space group
P
2
1
/
c
,
Z
= 2. The Co
2+
ions in compound
I
are joined in pairs by bridging ligands μ
2
-Detba
–
−O,O'. In addition, each of them is linked through the O atoms to one terminal Detba–ion and two BuOH molecules to form a trigonal bipyramid СоО
5
. Hydrogen bonds O–H···O formed by BuOH and Detba
–
join the binuclear complexes into an infinite chain. The data of IR spectroscopy are consistent with the results of X-ray diffraction analysis. |
| doi_str_mv | 10.1134/S1070328417010031 |
| format | article |
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2
(BuOH)
4
(Detba)
4
] (
I
), where НDetba is 1,3-diethyl-2-thiobarbituric acid, and BuOH is butanol-1, is determined (CIF file CCDC 1475273), and its IR spectrum is studied. The crystals are monoclinic:
a
= 10.7185(5),
b
= 21.985(1),
c
= 12.7235(7) Å, β = 92.196(2)°,
V
= 2996.1(3) Å
3
, space group
P
2
1
/
c
,
Z
= 2. The Co
2+
ions in compound
I
are joined in pairs by bridging ligands μ
2
-Detba
–
−O,O'. In addition, each of them is linked through the O atoms to one terminal Detba–ion and two BuOH molecules to form a trigonal bipyramid СоО
5
. Hydrogen bonds O–H···O formed by BuOH and Detba
–
join the binuclear complexes into an infinite chain. The data of IR spectroscopy are consistent with the results of X-ray diffraction analysis.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328417010031</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Butanol ; Chemical bonds ; Chemistry ; Chemistry and Materials Science ; Cobalt ; Hydrogen bonds ; Infrared spectroscopy ; Inorganic Chemistry ; Physical Chemistry ; Thiobarbituric acid</subject><ispartof>Russian journal of coordination chemistry, 2017-02, Vol.43 (2), p.82-85</ispartof><rights>Pleiades Publishing, Ltd. 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-10b3b6fd45a634884cdf9a7fcd608ee4a81975fbcb231f9239c58856604a867d3</citedby><cites>FETCH-LOGICAL-c316t-10b3b6fd45a634884cdf9a7fcd608ee4a81975fbcb231f9239c58856604a867d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Golovnev, N. N.</creatorcontrib><creatorcontrib>Molokeev, M. S.</creatorcontrib><creatorcontrib>Smolentsev, A. I.</creatorcontrib><creatorcontrib>Lesnikov, M. K.</creatorcontrib><title>Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II)</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>The structure of the dimeric complex [Co
2
(BuOH)
4
(Detba)
4
] (
I
), where НDetba is 1,3-diethyl-2-thiobarbituric acid, and BuOH is butanol-1, is determined (CIF file CCDC 1475273), and its IR spectrum is studied. The crystals are monoclinic:
a
= 10.7185(5),
b
= 21.985(1),
c
= 12.7235(7) Å, β = 92.196(2)°,
V
= 2996.1(3) Å
3
, space group
P
2
1
/
c
,
Z
= 2. The Co
2+
ions in compound
I
are joined in pairs by bridging ligands μ
2
-Detba
–
−O,O'. In addition, each of them is linked through the O atoms to one terminal Detba–ion and two BuOH molecules to form a trigonal bipyramid СоО
5
. Hydrogen bonds O–H···O formed by BuOH and Detba
–
join the binuclear complexes into an infinite chain. The data of IR spectroscopy are consistent with the results of X-ray diffraction analysis.</description><subject>Butanol</subject><subject>Chemical bonds</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Cobalt</subject><subject>Hydrogen bonds</subject><subject>Infrared spectroscopy</subject><subject>Inorganic Chemistry</subject><subject>Physical Chemistry</subject><subject>Thiobarbituric acid</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kE9LAzEQxYMoWKsfwFvByy4YzWx2k-xRin8KFQ_V85JkE7t1bWqSPfTbm6UeBPEwzMD7vZnhIXQJ5AaAlrcrIJzQQpTACRBC4QhNgBGBKQVxnOYk41E_RWchbMgIVfUEPa-iH3QcvJk5O4smevnRhSyDa4rbzsT1vscFjuvOKelVl0AZXZ6pIcqt6zHkedvppPUxWyzyc3RiZR_MxU-foreH-9f5E16-PC7md0usKbCIgSiqmG3LSjJaClHq1taSW92mj40ppYCaV1ZpVVCwdUFrXQlRMUaSxHhLp-jqsHfn3ddgQmw2bvDbdLIBIQhnqXii4EBp70LwxjY7331Kv2-ANGNqzZ_Ukqc4eEJit-_G_9r8r-kbOl5sAw</recordid><startdate>20170201</startdate><enddate>20170201</enddate><creator>Golovnev, N. N.</creator><creator>Molokeev, M. S.</creator><creator>Smolentsev, A. I.</creator><creator>Lesnikov, M. K.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170201</creationdate><title>Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II)</title><author>Golovnev, N. N. ; Molokeev, M. S. ; Smolentsev, A. I. ; Lesnikov, M. K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-10b3b6fd45a634884cdf9a7fcd608ee4a81975fbcb231f9239c58856604a867d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Butanol</topic><topic>Chemical bonds</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Cobalt</topic><topic>Hydrogen bonds</topic><topic>Infrared spectroscopy</topic><topic>Inorganic Chemistry</topic><topic>Physical Chemistry</topic><topic>Thiobarbituric acid</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Golovnev, N. N.</creatorcontrib><creatorcontrib>Molokeev, M. S.</creatorcontrib><creatorcontrib>Smolentsev, A. I.</creatorcontrib><creatorcontrib>Lesnikov, M. K.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Golovnev, N. N.</au><au>Molokeev, M. S.</au><au>Smolentsev, A. I.</au><au>Lesnikov, M. K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II)</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2017-02-01</date><risdate>2017</risdate><volume>43</volume><issue>2</issue><spage>82</spage><epage>85</epage><pages>82-85</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>The structure of the dimeric complex [Co
2
(BuOH)
4
(Detba)
4
] (
I
), where НDetba is 1,3-diethyl-2-thiobarbituric acid, and BuOH is butanol-1, is determined (CIF file CCDC 1475273), and its IR spectrum is studied. The crystals are monoclinic:
a
= 10.7185(5),
b
= 21.985(1),
c
= 12.7235(7) Å, β = 92.196(2)°,
V
= 2996.1(3) Å
3
, space group
P
2
1
/
c
,
Z
= 2. The Co
2+
ions in compound
I
are joined in pairs by bridging ligands μ
2
-Detba
–
−O,O'. In addition, each of them is linked through the O atoms to one terminal Detba–ion and two BuOH molecules to form a trigonal bipyramid СоО
5
. Hydrogen bonds O–H···O formed by BuOH and Detba
–
join the binuclear complexes into an infinite chain. The data of IR spectroscopy are consistent with the results of X-ray diffraction analysis.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328417010031</doi><tpages>4</tpages></addata></record> |
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| identifier | ISSN: 1070-3284 |
| ispartof | Russian journal of coordination chemistry, 2017-02, Vol.43 (2), p.82-85 |
| issn | 1070-3284 1608-3318 |
| language | eng |
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| source | Springer Nature |
| subjects | Butanol Chemical bonds Chemistry Chemistry and Materials Science Cobalt Hydrogen bonds Infrared spectroscopy Inorganic Chemistry Physical Chemistry Thiobarbituric acid |
| title | Structure of tetrakis((1,3-diethyl-2-thiobarbiturato)(butanol-1))dicobalt(II) |
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