Electrochemical determination of thermodynamic properties of saturated solid solutions of Hg2GeSe3, Hg2GeSe4, Ag2Hg3GeSe6, and Ag1.4Hg1.3GeSe6 compounds in the Ag–Hg–Ge–Se system

• Published in: Journal of solid state electrochemistry 2017-03, Vol.21 (3), p.833-837
• Main Authors: Moroz, M.V., Prokhorenko, M.V., Reshetnyak, O.V., Demchenko, P.Yu
• Format: Article
• Language: English
• Subjects: Analytical Chemistry; Characterization and Evaluation of Materials; Chemical reactions; Chemistry; Chemistry and Materials Science; Condensed Matter Physics; Differential equations; Differential thermal analysis; Electrochemical cells; Electrochemistry; Electrodes; Electrolytic cells; Energy Storage; Original Paper; Physical Chemistry; Selenium; Silver; Solid solutions; Thermodynamic properties; Thermodynamics; Triangulation
• ISSN: 1432-8488; 1433-0768
• DOI: 10.1007/s10008-016-3424-z

Triangulation of the Ag–Hg–Ge–Se system in the vicinity of GeSe 2 , HgSe, Hg 2 GeSe 3 , Hg 2 GeSe 4 , Ag 2 Hg 3 GeSe 6 , and Ag 1.4 Hg 1.3 GeSe 6 compounds and selenium was performed using X-ray diffraction and differential thermal analysis methods. The spatial position of the determined four-phase regions regarding figurative point of silver was used to write the equations of virtual potential-forming chemical reactions. Potential-forming processes were performed in electrochemical cells (ECCs) of the type (−) C | Ag | Ag 3 GeS 3 I glass | D | C (+) where C are the inert (graphite) electrodes, Ag and D are the electrodes of the ECCs, D represents equilibrium four-phase alloys, and Ag 3 GeS 3 I glass is a membrane with purely ionic Ag + conductivity. The linear dependences of the EMF of galvanic cells on temperature in the range of 425–455 K were used to calculate the standard thermodynamic values of saturated solid solutions of Hg 2 GeSe 3 , Hg 2 GeSe 4 , Ag 2 Hg 3 GeSe 6 , and Ag 1.4 Hg 1.3 GeSe 6 compounds.