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Spin canting in ferrite nanoparticles
Recently, an easily scalable process for the production of small (3 −7 nm) monodisperse superparamagnetic ferrite nanoparticles MeFe 2 O 4 (Me = Zn, Mn, Co) from iron metal and octanoic acid has been reported (Salih et al., Chem. Mater. 25 1430–1435 2013 ). Here we present a Mössbauer spectroscopic...
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| Published in: | Hyperfine interactions 2016-12, Vol.237 (1), p.1-8, Article 41 |
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| creator | Marx, J. Huang, H. M. Salih, K. S. Thiel, W. R. Schünemann, V. |
| description | Recently, an easily scalable process for the production of small (3 −7 nm) monodisperse superparamagnetic ferrite nanoparticles MeFe
2
O
4
(Me = Zn, Mn, Co) from iron metal and octanoic acid has been reported (Salih et al., Chem. Mater.
25
1430–1435
2013
). Here we present a Mössbauer spectroscopic study of these ferrite nanoparticles in external magnetic fields of up to B = 5 T at liquid helium temperatures. Our analysis shows that all three systems show a comparable inversion degree and the cationic distribution for the tetrahedral A and the octahedral B sites has been determined to (Zn
0.19
Fe
0.81
)
A
[Zn
0.81
Fe
1.19
]
B
O
4
, (Mn
0.15
Fe
0.85
)
A
[Mn
0.85
Fe
1.15
]
B
O
4
and (Co
0.27
Fe
0.73
)
A
[Co
0.73
Fe
1.27
]
B
O
4
. Spin canting occurs presumably in the B-sites and spin canting angles of 33°, 51° and 59° have been determined for the zinc, the manganese, and the cobalt ferrite nanoparticles. |
| doi_str_mv | 10.1007/s10751-016-1241-5 |
| format | article |
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2
O
4
(Me = Zn, Mn, Co) from iron metal and octanoic acid has been reported (Salih et al., Chem. Mater.
25
1430–1435
2013
). Here we present a Mössbauer spectroscopic study of these ferrite nanoparticles in external magnetic fields of up to B = 5 T at liquid helium temperatures. Our analysis shows that all three systems show a comparable inversion degree and the cationic distribution for the tetrahedral A and the octahedral B sites has been determined to (Zn
0.19
Fe
0.81
)
A
[Zn
0.81
Fe
1.19
]
B
O
4
, (Mn
0.15
Fe
0.85
)
A
[Mn
0.85
Fe
1.15
]
B
O
4
and (Co
0.27
Fe
0.73
)
A
[Co
0.73
Fe
1.27
]
B
O
4
. Spin canting occurs presumably in the B-sites and spin canting angles of 33°, 51° and 59° have been determined for the zinc, the manganese, and the cobalt ferrite nanoparticles.</description><identifier>ISSN: 0304-3843</identifier><identifier>EISSN: 1572-9540</identifier><identifier>DOI: 10.1007/s10751-016-1241-5</identifier><language>eng</language><publisher>Cham: Springer International Publishing</publisher><subject>13-18 September 2015 ; Atomic ; Cobalt ferrites ; Condensed Matter Physics ; Filing ; Germany ; Hadrons ; Hamburg ; Heavy Ions ; Helium ; Liquid helium ; Manganese ; Molecular ; Nanoparticles ; Nuclear Physics ; Octanoic acid ; Optical and Plasma Physics ; Physics ; Physics and Astronomy ; Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME 2015) ; Surfaces and Interfaces ; Thin Films ; Zinc</subject><ispartof>Hyperfine interactions, 2016-12, Vol.237 (1), p.1-8, Article 41</ispartof><rights>Springer International Publishing Switzerland 2016</rights><rights>Copyright Springer Science & Business Media 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-9b1f12d0c9eb97fd917175dc71e37a2b2dff4266d3b385f97e45320f5150e1ba3</citedby><cites>FETCH-LOGICAL-c316t-9b1f12d0c9eb97fd917175dc71e37a2b2dff4266d3b385f97e45320f5150e1ba3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27915,27916</link.rule.ids></links><search><creatorcontrib>Marx, J.</creatorcontrib><creatorcontrib>Huang, H.</creatorcontrib><creatorcontrib>M. Salih, K. S.</creatorcontrib><creatorcontrib>Thiel, W. R.</creatorcontrib><creatorcontrib>Schünemann, V.</creatorcontrib><title>Spin canting in ferrite nanoparticles</title><title>Hyperfine interactions</title><addtitle>Hyperfine Interact</addtitle><description>Recently, an easily scalable process for the production of small (3 −7 nm) monodisperse superparamagnetic ferrite nanoparticles MeFe
2
O
4
(Me = Zn, Mn, Co) from iron metal and octanoic acid has been reported (Salih et al., Chem. Mater.
25
1430–1435
2013
). Here we present a Mössbauer spectroscopic study of these ferrite nanoparticles in external magnetic fields of up to B = 5 T at liquid helium temperatures. Our analysis shows that all three systems show a comparable inversion degree and the cationic distribution for the tetrahedral A and the octahedral B sites has been determined to (Zn
0.19
Fe
0.81
)
A
[Zn
0.81
Fe
1.19
]
B
O
4
, (Mn
0.15
Fe
0.85
)
A
[Mn
0.85
Fe
1.15
]
B
O
4
and (Co
0.27
Fe
0.73
)
A
[Co
0.73
Fe
1.27
]
B
O
4
. Spin canting occurs presumably in the B-sites and spin canting angles of 33°, 51° and 59° have been determined for the zinc, the manganese, and the cobalt ferrite nanoparticles.</description><subject>13-18 September 2015</subject><subject>Atomic</subject><subject>Cobalt ferrites</subject><subject>Condensed Matter Physics</subject><subject>Filing</subject><subject>Germany</subject><subject>Hadrons</subject><subject>Hamburg</subject><subject>Heavy Ions</subject><subject>Helium</subject><subject>Liquid helium</subject><subject>Manganese</subject><subject>Molecular</subject><subject>Nanoparticles</subject><subject>Nuclear Physics</subject><subject>Octanoic acid</subject><subject>Optical and Plasma Physics</subject><subject>Physics</subject><subject>Physics and Astronomy</subject><subject>Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME 2015)</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><subject>Zinc</subject><issn>0304-3843</issn><issn>1572-9540</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kD1PwzAURS0EEqXwA9giIUbDe_6I4xFVUJAqMQCz5Th2lao4wU4H_j2uwsDC9O5wz33SIeQa4Q4B1H1GUBIpYE2RCaTyhCxQKka1FHBKFsBBUN4Ifk4uct4BAFOoF-T2bexj5Wyc-ritSgw-pX7yVbRxGG2aerf3-ZKcBbvP_ur3LsnH0-P76pluXtcvq4cNdRzrieoWA7IOnPatVqHTqFDJzin0XFnWsi4Eweq64y1vZNDKC8kZBIkSPLaWL8nNvDum4evg82R2wyHF8tJg04BqpOCqtHBuuTTknHwwY-o_bfo2COZow8w2TLFhjjaMLAybmVy6cevTn-V_oR-6qmBM</recordid><startdate>20161201</startdate><enddate>20161201</enddate><creator>Marx, J.</creator><creator>Huang, H.</creator><creator>M. Salih, K. S.</creator><creator>Thiel, W. R.</creator><creator>Schünemann, V.</creator><general>Springer International Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20161201</creationdate><title>Spin canting in ferrite nanoparticles</title><author>Marx, J. ; Huang, H. ; M. Salih, K. S. ; Thiel, W. R. ; Schünemann, V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-9b1f12d0c9eb97fd917175dc71e37a2b2dff4266d3b385f97e45320f5150e1ba3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>13-18 September 2015</topic><topic>Atomic</topic><topic>Cobalt ferrites</topic><topic>Condensed Matter Physics</topic><topic>Filing</topic><topic>Germany</topic><topic>Hadrons</topic><topic>Hamburg</topic><topic>Heavy Ions</topic><topic>Helium</topic><topic>Liquid helium</topic><topic>Manganese</topic><topic>Molecular</topic><topic>Nanoparticles</topic><topic>Nuclear Physics</topic><topic>Octanoic acid</topic><topic>Optical and Plasma Physics</topic><topic>Physics</topic><topic>Physics and Astronomy</topic><topic>Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME 2015)</topic><topic>Surfaces and Interfaces</topic><topic>Thin Films</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Marx, J.</creatorcontrib><creatorcontrib>Huang, H.</creatorcontrib><creatorcontrib>M. Salih, K. S.</creatorcontrib><creatorcontrib>Thiel, W. R.</creatorcontrib><creatorcontrib>Schünemann, V.</creatorcontrib><collection>CrossRef</collection><jtitle>Hyperfine interactions</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Marx, J.</au><au>Huang, H.</au><au>M. Salih, K. S.</au><au>Thiel, W. R.</au><au>Schünemann, V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Spin canting in ferrite nanoparticles</atitle><jtitle>Hyperfine interactions</jtitle><stitle>Hyperfine Interact</stitle><date>2016-12-01</date><risdate>2016</risdate><volume>237</volume><issue>1</issue><spage>1</spage><epage>8</epage><pages>1-8</pages><artnum>41</artnum><issn>0304-3843</issn><eissn>1572-9540</eissn><abstract>Recently, an easily scalable process for the production of small (3 −7 nm) monodisperse superparamagnetic ferrite nanoparticles MeFe
2
O
4
(Me = Zn, Mn, Co) from iron metal and octanoic acid has been reported (Salih et al., Chem. Mater.
25
1430–1435
2013
). Here we present a Mössbauer spectroscopic study of these ferrite nanoparticles in external magnetic fields of up to B = 5 T at liquid helium temperatures. Our analysis shows that all three systems show a comparable inversion degree and the cationic distribution for the tetrahedral A and the octahedral B sites has been determined to (Zn
0.19
Fe
0.81
)
A
[Zn
0.81
Fe
1.19
]
B
O
4
, (Mn
0.15
Fe
0.85
)
A
[Mn
0.85
Fe
1.15
]
B
O
4
and (Co
0.27
Fe
0.73
)
A
[Co
0.73
Fe
1.27
]
B
O
4
. Spin canting occurs presumably in the B-sites and spin canting angles of 33°, 51° and 59° have been determined for the zinc, the manganese, and the cobalt ferrite nanoparticles.</abstract><cop>Cham</cop><pub>Springer International Publishing</pub><doi>10.1007/s10751-016-1241-5</doi><tpages>8</tpages></addata></record> |
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| issn | 0304-3843 1572-9540 |
| language | eng |
| recordid | cdi_proquest_journals_1880785437 |
| source | Springer Nature |
| subjects | 13-18 September 2015 Atomic Cobalt ferrites Condensed Matter Physics Filing Germany Hadrons Hamburg Heavy Ions Helium Liquid helium Manganese Molecular Nanoparticles Nuclear Physics Octanoic acid Optical and Plasma Physics Physics Physics and Astronomy Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME 2015) Surfaces and Interfaces Thin Films Zinc |
| title | Spin canting in ferrite nanoparticles |
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