Reaction of O,O-dialkyldithiophosphoric acid with N-tert-butyl-2,2-dihalopropanimines

O,O -Dialkyldithiophosphoric acid reacted with N - tert -butyl-2,2-dihalopropanimines to give iminium salt as a primary product, which further sequentially undergoes reaction with two equivalents of dithiophosphoric acid to initially reduce the C—X (X = Cl, Br) bond in the iminium salt and then nucl...

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Bibliographic Details
Published in:Russian chemical bulletin 2016-04, Vol.65 (4), p.1119-1121
Main Authors: Gazizov, M. B., Khairullin, R. A., Aksenov, N. G., Kirillina, Yu. S., Bandikova, A. Yu
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Full Articles
Inorganic Chemistry
Organic Chemistry
Reaction products
Substitution reactions
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Summary:O,O -Dialkyldithiophosphoric acid reacted with N - tert -butyl-2,2-dihalopropanimines to give iminium salt as a primary product, which further sequentially undergoes reaction with two equivalents of dithiophosphoric acid to initially reduce the C—X (X = Cl, Br) bond in the iminium salt and then nucleophilic replacement of the halogen atom with dialkoxydithiophosphate group. The final reaction products are the reduction—substitution product of the primary salt and bis(dialkoxythiophosphoryl) disulfide.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-016-1422-z