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Anodic dissolution of tin in alcohols

Tin(II) alcoholates Sn(OR) 2 are formed upon the anodic galvanostatic dissolution of tin in alcohols in an undivided cell in the presence of minimum amounts of NaOAc as an electrolyte. Tin(II) alcoholates are easily hydrolyzed in air to form oxyhydroxide Sn 3 O 2 (OН) 2 used as an anode or its compo...

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Bibliographic Details
Published in:Russian chemical bulletin 2016-03, Vol.65 (3), p.840-843
Main Authors: Vereshchagin, A. N., Elinson, M. N., Goloveshkin, A. S., Novikov, R. A., Egorov, M. P.
Format: Article
Language:English
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Summary:Tin(II) alcoholates Sn(OR) 2 are formed upon the anodic galvanostatic dissolution of tin in alcohols in an undivided cell in the presence of minimum amounts of NaOAc as an electrolyte. Tin(II) alcoholates are easily hydrolyzed in air to form oxyhydroxide Sn 3 O 2 (OН) 2 used as an anode or its composite component in lithium cells.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-016-1387-y