Nucleophilic substitution in 4-bromo-5-nitrophthalonitrile: XIV. Synthesis and properties of 4,5-bis[4-(1-methyl-1-phenylethyl)phenoxy]phthalonitrile and phthalocyanines therefrom

4,5-Bis[4-(1-methyl-1-phenylethyl)phenoxy]phthalonitrile was prepared by the nucleophilic substitution of the nitro group and bromine in 4-bromo-5-nitrophathalonitrile. The product was used to synthesize the corresponding octasubstituted phthalocyanine, as well as its magnesium, copper, zinc, cobalt...

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Bibliographic Details
Published in:Russian journal of general chemistry 2016-11, Vol.86 (11), p.2501-2507
Main Authors: Znoiko, S. A., Serova, M. A., Uspenskaya, A. A., Zav’yalov, A. V., Maizlish, V. E., Shaposhnikov, G. P.
Format: Article
Language:English
Subjects:
Bromine
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Magnesium
Synthesis
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Summary:4,5-Bis[4-(1-methyl-1-phenylethyl)phenoxy]phthalonitrile was prepared by the nucleophilic substitution of the nitro group and bromine in 4-bromo-5-nitrophathalonitrile. The product was used to synthesize the corresponding octasubstituted phthalocyanine, as well as its magnesium, copper, zinc, cobalt, and nickel complexes. The spectral properties of the synthesized phthalocyanines were studied.
ISSN:1070-3632
1608-3350
DOI:10.1134/S1070363216110165