Crystal structures, thermal properties, and luminescent properties of two novel mononuclear lanthanide complexes with 2,4-dichlorobenzoic acid and 2,2′:6′,2″-terpyridine

Two novel mononuclear lanthanide complexes, [Ln(2,4-DClBA) 3 (terpy)(H 2 O)]·H 2 O (Ln = Dy(1), Er(2)); 2,4-DClBA: 2,4-dichlorobenzoate; terpy: 2,2′:6′,2″-terpyridine; have been synthesized and characterized by single-crystal and powder X-ray diffraction. The results reveal that complexes 1–2 are is...

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Bibliographic Details
Published in:Journal of thermal analysis and calorimetry 2016-12, Vol.126 (3), p.1703-1712
Main Authors: Wang, Ye, Zhao, Qing-Qing, Ren, Ning, Zhang, Jian-Jun, Geng, Li-Na, Wang, Shu-Ping
Format: Article
Language:English
Subjects:
Activation energy
Analysis
Analytical Chemistry
Chemistry
Chemistry and Materials Science
Crystal structure
Crystals
Diffraction
Hydrogen
Inorganic Chemistry
Measurement Science and Instrumentation
Physical Chemistry
Polymer Sciences
Rare earth metals
Structure
Thermal decomposition
Thermal properties
Thermodynamic properties
X-rays
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Summary:Two novel mononuclear lanthanide complexes, [Ln(2,4-DClBA) 3 (terpy)(H 2 O)]·H 2 O (Ln = Dy(1), Er(2)); 2,4-DClBA: 2,4-dichlorobenzoate; terpy: 2,2′:6′,2″-terpyridine; have been synthesized and characterized by single-crystal and powder X-ray diffraction. The results reveal that complexes 1–2 are isomorphous, and each Ln 3+ ion is nine coordinated adopting a distorted monocapped square antiprismatic molecular geometry. Mononuclear complexes 1–2 are stitched together via Cl– π and hydrogen bonding interactions to form the 1D, 2D, 3D supramolecular structures, which the 3D is rarely observed. Thermal decomposition mechanism is determined by TG/DSC-FTIR, and the 3D stacked plots for the FTIR spectra of the evolved gases were recorded. Heat capacities of complexes 1–2 were measured, and the derived thermodynamic functions ( H T  −  H 298.15 ), ( S T  −  S 298.15 ) and ( G T  −  G 298.15 ) of the complexes relative to the standard reference temperature 298.15 K were obtained. The activation energy E values of the first decomposition stage for title complexes were calculated by integral isoconversional nonlinear (NL-INT) and Starink methods. Complex 1 shows the characteristic emission of Dy 3+ with strong yellow emission.
ISSN:1388-6150
1588-2926
DOI:10.1007/s10973-016-5728-8