Polyarenes prepared by Suzuki–Miyaura reaction via condensation of sumanene and 3,4:9,10-perylenetetracarboxydiimide derivatives: Synthesis and chemical transformations

A sumanene-containing polyarene with side epoxy groups has been obtained for the first time by the sequential chemical transformations of initial polyarene. The latter was prepared by the condensation of diiodosumanene and diboryl derivative of perylenetetracarboxydiimide. The epoxy-containing polya...

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Bibliographic Details
Published in:Doklady. Chemistry 2016-10, Vol.470 (2), p.289-292
Main Authors: Vainer, A. Ya, Dyumaev, K. M., Kovalenko, A. M., Bel’skii, T. D., Vishnyakov, A. V., Krichevskaya, S. A.
Format: Article
Language:English
Subjects:
Chemical reactions
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Industrial Chemistry/Chemical Engineering
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Summary:A sumanene-containing polyarene with side epoxy groups has been obtained for the first time by the sequential chemical transformations of initial polyarene. The latter was prepared by the condensation of diiodosumanene and diboryl derivative of perylenetetracarboxydiimide. The epoxy-containing polyarene can provide a basis for promising negative electron resist for 12-nanometer chip manufacturing technology.
ISSN:0012-5008
1608-3113
DOI:10.1134/S0012500816100037