Preparation and Reactivity of Metal-Containing Monomers. 78. Scandium-Containing Monomers And Polymers: Synthesis, Structure and Properties

The Sc(III)-containing monomers and their (co)polymers has been first prepared and characterized. The composition and structure of the synthesized metal-containing monomers and (co)polymers examined by elemental analysis, IR and 13 C-NMR spectroscopy. The thermal behavior of Sc(III)—containing monom...

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Bibliographic Details
Published in:Journal of inorganic and organometallic polymers and materials 2016-11, Vol.26 (6), p.1441-1451
Main Authors: Dzhardimalieva, G. I., Semenov, S. A., Knerelman, E. I., Davydova, G. I., Kydralieva, K. A.
Format: Article
Language:English
Subjects:
Chemical analysis
Chemical synthesis
Chemistry
Chemistry and Materials Science
Copolymers
Differential thermal analysis
Infrared spectroscopy
Inorganic Chemistry
Mass spectrometry
Monomers
NMR spectroscopy
Organic Chemistry
Polymer Sciences
Polymers
Scandium
Sorbents
Structural stability
Thermal stability
Thermodynamic properties
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Summary:The Sc(III)-containing monomers and their (co)polymers has been first prepared and characterized. The composition and structure of the synthesized metal-containing monomers and (co)polymers examined by elemental analysis, IR and 13 C-NMR spectroscopy. The thermal behavior of Sc(III)—containing monomers and (co)polymers was explored by DSC, DTA, TGA and mass spectrometry. It is shown that the obtained crosslinked copolymers exhibit a high thermal stability, have a porous structure with a developed system of micro- and mesopores, which may be of interest for their template-based customized sorbents for concentration and extraction of scandium.
ISSN:1574-1443
1574-1451
DOI:10.1007/s10904-016-0421-8