Characteristics of non-platinum cathode catalysts for a hydrogen–oxygen fuel cell with proton- and anion-conducting electrolytes

• Published in: Catalysis in industry 2016-07, Vol.8 (3), p.265-273
• Main Authors: Korchagin, O. V., Bogdanovskaya, V. A., Tarasevich, M. R., Kuzov, A. V., Zhutaeva, G. V., Radina, M. V., Novikov, V. T., Zharikov, V. V.
• Format: Article
• Language: English
• Subjects: Anions; Assembly; Carbon; Catalysis; Catalysts; Cathodes; Chemical reduction; Chemical synthesis; Chemistry; Chemistry and Materials Science; Cobalt compounds; Electrocatalysis; Electrodes; Electrolytes; Fuel cells; Hydrogen; Hydrogen oxygen fuel cells; Iron; Iron compounds; Membranes; Nitrogen; Oxygen reduction reactions; Photoelectrons; Platinum; Protons; Pyrolysis; X ray photoelectron spectroscopy
• ISSN: 2070-0504; 2070-0555
• DOI: 10.1134/S2070050416030053

Cathode catalysts for a hydrogen–oxygen fuel cell (FC) with proton-conducting (acidic) and anion-conducting (alkaline) electrolytes are synthesized via the pyrolysis of nitrogen-containing iron and cobalt complexes on the surfaces of highly disperse carbon materials. The catalysts are characterized by X-ray photoelectron spectroscopy (XPS) and tested under model conditions on a thin-layer disk electrode and as a part of a membrane electrode assembly of hydrogen–oxygen FCs. The properties of the CoFe/C system formed via the pyrolysis of macroheterocyclic cobalt and iron compounds on carbon materials (XC-72 soot and multiwall nanotubes (MNTs)) are described for the first time. According to XPS data, the surface of the CoFe/C catalytic systems is enriched with carbon (95.5 at %) and contains nitrogen (2 at %), oxygen (2 at %), and metals (0.5 at %). According to the results from electrochemical measurements under model conditions, the CoFe/MNT catalytic systems approaches 60% Pt/C (HiSPEC9100) commercial platinum catalyst according to their activity in the oxygen reduction reaction in an alkaline medium (0.5 M KOH). The half-wave potentials are 0.85 and 0.88 V for CoFe/MNT and 60% Pt/C (HiSPEC9100) catalysts, respectively. The maximum specific powers of hydrogen–oxygen FCs with anion-conducting electrolytes are 210 mW/cm 2 (60% Pt/C (HiSPEC9100) based cathode) and 180 mW/cm 2 (CoFe/MNT based cathode). The characteristics of a membrane electrode assembly with a non-platinum cathode correspond to the best analogs described in the literature. The results of this work show the prospects for further studies on scaling this technology for the synthesis of the proposed non-platinum cathode catalysts and optimizing the architecture of the membrane electrode assembly of FCs based on them.