Theory of the first encounter with the boundary by a stochastic diffusion process in an equilibrium electrochemical RC-circuit

The methodology of electrochemial impedance is used for finding the characteristic function of the random time of the first encounter with the boundary by a process of electrochemical stochastic diffusion in an equilibrium ac circuit containing a double layer capacitance and a noisy charge-transfer...

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Bibliographic Details
Published in:Russian journal of electrochemistry 2016-09, Vol.52 (9), p.885-889
Main Author: Grafov, B. M.
Format: Article
Language:English
Subjects:
Characteristic functions
Chemistry
Chemistry and Materials Science
Comparative studies
Corrosion resistance
Diffusion layers
Electrochemical corrosion
Electrochemistry
Nyquist plots
Physical Chemistry
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Summary:The methodology of electrochemial impedance is used for finding the characteristic function of the random time of the first encounter with the boundary by a process of electrochemical stochastic diffusion in an equilibrium ac circuit containing a double layer capacitance and a noisy charge-transfer resistance. The Nyquist diagram of the characteristic function suggests that the method of the first random encounter with the boundary by electrochemical stochastic diffusion may prove to be useful in the noise diagnosis of objects and devices of electrochemical power engineering and also in comparative studies of electrochemical corrosion processes.
ISSN:1023-1935
1608-3342
DOI:10.1134/S1023193516090044