Palladium acetate complexes in the gas phase

New palladium acetate complexes, Pd 2 (OOCMe) 4 + , Pd 2 (OOCMe) 3 + , Pd 2 (OOCMe) 2 + , and Pd 2 (OOCMe) + were detected in the thermal decomposition products of trans -Pd(Py) 2 (OOCMe) 2 by mass spectrometry with direct ion source. The geometric and electronic structures of the Pd 2 (μ-OOCMe) 4 +...

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Bibliographic Details
Published in:Russian journal of coordination chemistry 2016-09, Vol.42 (9), p.604-607
Main Authors: Yakushev, I. Ya, Gekhman, A. E., Klyagina, A. P., Markov, A. A., Vargaftik, M. N., Stolyarov, I. P., Cherkashina, N. V., Kornev, A. B., Moiseev, I. I.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Inorganic Chemistry
Ion sources
Mass spectrometry
Palladium
Physical Chemistry
Quantum chemistry
Thermal decomposition
Vapor phases
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Summary:New palladium acetate complexes, Pd 2 (OOCMe) 4 + , Pd 2 (OOCMe) 3 + , Pd 2 (OOCMe) 2 + , and Pd 2 (OOCMe) + were detected in the thermal decomposition products of trans -Pd(Py) 2 (OOCMe) 2 by mass spectrometry with direct ion source. The geometric and electronic structures of the Pd 2 (μ-OOCMe) 4 + cation and the Pd 2 (OOCMe) 4 molecule were established by quantum chemical calculations (DFT with the PBE1PBE hybrid exchange correlation potential in the 6-31G*/SDD basis set) and natural orbital analysis.
ISSN:1070-3284
1608-3318
DOI:10.1134/S1070328416090098