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Palladium acetate complexes in the gas phase
New palladium acetate complexes, Pd 2 (OOCMe) 4 + , Pd 2 (OOCMe) 3 + , Pd 2 (OOCMe) 2 + , and Pd 2 (OOCMe) + were detected in the thermal decomposition products of trans -Pd(Py) 2 (OOCMe) 2 by mass spectrometry with direct ion source. The geometric and electronic structures of the Pd 2 (μ-OOCMe) 4 +...
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| Published in: | Russian journal of coordination chemistry 2016-09, Vol.42 (9), p.604-607 |
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| Main Authors: | , , , , , , , , |
| Format: | Article |
| Language: | English |
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| cites | cdi_FETCH-LOGICAL-c316t-fb1458f64665247e7fad56853b4c1bbcb22861f9624efb3da3c57df2e13c081a3 |
| container_end_page | 607 |
| container_issue | 9 |
| container_start_page | 604 |
| container_title | Russian journal of coordination chemistry |
| container_volume | 42 |
| creator | Yakushev, I. Ya Gekhman, A. E. Klyagina, A. P. Markov, A. A. Vargaftik, M. N. Stolyarov, I. P. Cherkashina, N. V. Kornev, A. B. Moiseev, I. I. |
| description | New palladium acetate complexes, Pd
2
(OOCMe)
4
+
, Pd
2
(OOCMe)
3
+
, Pd
2
(OOCMe)
2
+
, and Pd
2
(OOCMe)
+
were detected in the thermal decomposition products of
trans
-Pd(Py)
2
(OOCMe)
2
by mass spectrometry with direct ion source. The geometric and electronic structures of the Pd
2
(μ-OOCMe)
4
+
cation and the Pd
2
(OOCMe)
4
molecule were established by quantum chemical calculations (DFT with the PBE1PBE hybrid exchange correlation potential in the 6-31G*/SDD basis set) and natural orbital analysis. |
| doi_str_mv | 10.1134/S1070328416090098 |
| format | article |
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2
(OOCMe)
4
+
, Pd
2
(OOCMe)
3
+
, Pd
2
(OOCMe)
2
+
, and Pd
2
(OOCMe)
+
were detected in the thermal decomposition products of
trans
-Pd(Py)
2
(OOCMe)
2
by mass spectrometry with direct ion source. The geometric and electronic structures of the Pd
2
(μ-OOCMe)
4
+
cation and the Pd
2
(OOCMe)
4
molecule were established by quantum chemical calculations (DFT with the PBE1PBE hybrid exchange correlation potential in the 6-31G*/SDD basis set) and natural orbital analysis.</description><identifier>ISSN: 1070-3284</identifier><identifier>EISSN: 1608-3318</identifier><identifier>DOI: 10.1134/S1070328416090098</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Chemistry ; Chemistry and Materials Science ; Inorganic Chemistry ; Ion sources ; Mass spectrometry ; Palladium ; Physical Chemistry ; Quantum chemistry ; Thermal decomposition ; Vapor phases</subject><ispartof>Russian journal of coordination chemistry, 2016-09, Vol.42 (9), p.604-607</ispartof><rights>Pleiades Publishing, Ltd. 2016</rights><rights>Copyright Springer Science & Business Media 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-fb1458f64665247e7fad56853b4c1bbcb22861f9624efb3da3c57df2e13c081a3</citedby><cites>FETCH-LOGICAL-c316t-fb1458f64665247e7fad56853b4c1bbcb22861f9624efb3da3c57df2e13c081a3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Yakushev, I. Ya</creatorcontrib><creatorcontrib>Gekhman, A. E.</creatorcontrib><creatorcontrib>Klyagina, A. P.</creatorcontrib><creatorcontrib>Markov, A. A.</creatorcontrib><creatorcontrib>Vargaftik, M. N.</creatorcontrib><creatorcontrib>Stolyarov, I. P.</creatorcontrib><creatorcontrib>Cherkashina, N. V.</creatorcontrib><creatorcontrib>Kornev, A. B.</creatorcontrib><creatorcontrib>Moiseev, I. I.</creatorcontrib><title>Palladium acetate complexes in the gas phase</title><title>Russian journal of coordination chemistry</title><addtitle>Russ J Coord Chem</addtitle><description>New palladium acetate complexes, Pd
2
(OOCMe)
4
+
, Pd
2
(OOCMe)
3
+
, Pd
2
(OOCMe)
2
+
, and Pd
2
(OOCMe)
+
were detected in the thermal decomposition products of
trans
-Pd(Py)
2
(OOCMe)
2
by mass spectrometry with direct ion source. The geometric and electronic structures of the Pd
2
(μ-OOCMe)
4
+
cation and the Pd
2
(OOCMe)
4
molecule were established by quantum chemical calculations (DFT with the PBE1PBE hybrid exchange correlation potential in the 6-31G*/SDD basis set) and natural orbital analysis.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Inorganic Chemistry</subject><subject>Ion sources</subject><subject>Mass spectrometry</subject><subject>Palladium</subject><subject>Physical Chemistry</subject><subject>Quantum chemistry</subject><subject>Thermal decomposition</subject><subject>Vapor phases</subject><issn>1070-3284</issn><issn>1608-3318</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kEtLxEAQhAdRcF39Ad4CXo12zyuToyy6CgsK6jlMJj37ILuJMwnov3eW9SCIpy6or6qhGLtEuEEU8vYVoQDBjUQNJUBpjtgkSZMLgeY46WTne_-UncW4AUAAVU7Y9YttW9usx21mHQ12oMx1276lT4rZepcNK8qWNmb9ykY6ZyfetpEufu6UvT_cv80e88Xz_Gl2t8idQD3kvkapjNdSa8VlQYW3jdJGiVo6rGtXc240-lJzSb4WjRVOFY3nhMKBQSum7OrQ24fuY6Q4VJtuDLv0skJjwBSoFSYKD5QLXYyBfNWH9daGrwqh2o9S_RklZfghExO7W1L41fxv6Btzp2F4</recordid><startdate>20160901</startdate><enddate>20160901</enddate><creator>Yakushev, I. Ya</creator><creator>Gekhman, A. E.</creator><creator>Klyagina, A. P.</creator><creator>Markov, A. A.</creator><creator>Vargaftik, M. N.</creator><creator>Stolyarov, I. P.</creator><creator>Cherkashina, N. V.</creator><creator>Kornev, A. B.</creator><creator>Moiseev, I. I.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20160901</creationdate><title>Palladium acetate complexes in the gas phase</title><author>Yakushev, I. Ya ; Gekhman, A. E. ; Klyagina, A. P. ; Markov, A. A. ; Vargaftik, M. N. ; Stolyarov, I. P. ; Cherkashina, N. V. ; Kornev, A. B. ; Moiseev, I. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-fb1458f64665247e7fad56853b4c1bbcb22861f9624efb3da3c57df2e13c081a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Inorganic Chemistry</topic><topic>Ion sources</topic><topic>Mass spectrometry</topic><topic>Palladium</topic><topic>Physical Chemistry</topic><topic>Quantum chemistry</topic><topic>Thermal decomposition</topic><topic>Vapor phases</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yakushev, I. Ya</creatorcontrib><creatorcontrib>Gekhman, A. E.</creatorcontrib><creatorcontrib>Klyagina, A. P.</creatorcontrib><creatorcontrib>Markov, A. A.</creatorcontrib><creatorcontrib>Vargaftik, M. N.</creatorcontrib><creatorcontrib>Stolyarov, I. P.</creatorcontrib><creatorcontrib>Cherkashina, N. V.</creatorcontrib><creatorcontrib>Kornev, A. B.</creatorcontrib><creatorcontrib>Moiseev, I. I.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of coordination chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yakushev, I. Ya</au><au>Gekhman, A. E.</au><au>Klyagina, A. P.</au><au>Markov, A. A.</au><au>Vargaftik, M. N.</au><au>Stolyarov, I. P.</au><au>Cherkashina, N. V.</au><au>Kornev, A. B.</au><au>Moiseev, I. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Palladium acetate complexes in the gas phase</atitle><jtitle>Russian journal of coordination chemistry</jtitle><stitle>Russ J Coord Chem</stitle><date>2016-09-01</date><risdate>2016</risdate><volume>42</volume><issue>9</issue><spage>604</spage><epage>607</epage><pages>604-607</pages><issn>1070-3284</issn><eissn>1608-3318</eissn><abstract>New palladium acetate complexes, Pd
2
(OOCMe)
4
+
, Pd
2
(OOCMe)
3
+
, Pd
2
(OOCMe)
2
+
, and Pd
2
(OOCMe)
+
were detected in the thermal decomposition products of
trans
-Pd(Py)
2
(OOCMe)
2
by mass spectrometry with direct ion source. The geometric and electronic structures of the Pd
2
(μ-OOCMe)
4
+
cation and the Pd
2
(OOCMe)
4
molecule were established by quantum chemical calculations (DFT with the PBE1PBE hybrid exchange correlation potential in the 6-31G*/SDD basis set) and natural orbital analysis.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070328416090098</doi><tpages>4</tpages></addata></record> |
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| ispartof | Russian journal of coordination chemistry, 2016-09, Vol.42 (9), p.604-607 |
| issn | 1070-3284 1608-3318 |
| language | eng |
| recordid | cdi_proquest_journals_1880871651 |
| source | Springer Link |
| subjects | Chemistry Chemistry and Materials Science Inorganic Chemistry Ion sources Mass spectrometry Palladium Physical Chemistry Quantum chemistry Thermal decomposition Vapor phases |
| title | Palladium acetate complexes in the gas phase |
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