Base-oxidant promoted metal-free N-demethylation of arylamines

A metal-free oxidative N -demethylation of arylamines with triethylamine as a base and tert -butyl hydroperoxide (TBHP) as oxidant is reported in this paper. The reaction is general, practical, inexpensive, non-toxic, and the method followed is environmentally benign, with moderate to good yields. G...

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Published in:Journal of chemical sciences (Bangalore, India) India), 2016-09, Vol.128 (9), p.1469-1473
Main Authors: BOTLA, VINAYAK, BARREDDI, CHIRANJEEVI, DAGGUPATI, RAMANA V, MALAPAKA, CHANDRASEKHARAM
Format: Article
Language:English
Subjects:
Amines
Butyl hydroperoxide
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Organic compounds
Triethylamine
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description A metal-free oxidative N -demethylation of arylamines with triethylamine as a base and tert -butyl hydroperoxide (TBHP) as oxidant is reported in this paper. The reaction is general, practical, inexpensive, non-toxic, and the method followed is environmentally benign, with moderate to good yields. Graphical Abstract Here we report a metal-free oxidative N -demethylation of arylamines with triethylamine as a base and tert-butyl hydroperoxide (TBHP) as oxidant. The reaction is general, practical, inexpensive, nontoxic and an environmentally benign method, with moderate to good yields.
doi_str_mv 10.1007/s12039-016-1152-7
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subjects Amines
Butyl hydroperoxide
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Organic compounds
Triethylamine
title Base-oxidant promoted metal-free N-demethylation of arylamines
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