Complexation equilibria in tetrahydrofuran solutions of palladium(II) and lithium bromides

The solutions of palladium PdBr 2 and lithium LiBr bromides in tetrahydrofuran (THF) at different concentrations were studied by UV–Vis spectroscopy. The data obtained were mathematically processed using various models. The best description was obtained with the model that includes the formation of...

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Bibliographic Details
Published in:Russian Journal of Physical Chemistry A 2017-04, Vol.91 (4), p.697-707
Main Authors: Putin, A. Yu, Katsman, E. A., Temkin, O. N., Bruk, L. G.
Format: Article
Language:English
Subjects:
Bromides
Chemical equilibrium
Chemistry
Chemistry and Materials Science
Complexation
Dimers
Lithium
Monomers
Palladium
Physical Chemistry
Structure of Matter and Quantum Chemistry
Tetrahydrofuran
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Summary:The solutions of palladium PdBr 2 and lithium LiBr bromides in tetrahydrofuran (THF) at different concentrations were studied by UV–Vis spectroscopy. The data obtained were mathematically processed using various models. The best description was obtained with the model that includes the formation of four monomeric (PdBr + , PdBr 2 , PdBr 3 - , PdBr 4 2- ) and three dimeric (Pd 2 Br 2 2+ , Pd 2 Br 4 , Pd 2 Br 6 2- ) palladium complexes. The equilibrium constants of the monomer and dimer complexation stages and the extinction coefficients of the palladium complexes were calculated. The spectra of the individual monomer and dimer palladium complexes were calculated using this model.
ISSN:0036-0244
1531-863X
DOI:10.1134/S0036024417040227