Alkylation of 2-methylimidazole with iodomethylsilanes

2-Methyl-1,3-bis[(1-methylsilolan-1-yl)methyl]-1 H -imidazolium triiodide, 1,3-bis{[dimethyl-(phenyl)silyl]methyl}-2-methyl-1 H -imidazolium iodide and triiodide, and cyclic 3,3,5,5,10-pentamethyl-4-oxa-7-aza-1-azonia-3,5-disilabicyclo[5.2.1]deca-1(10),8-diene iodide were synthesized by solvent-free...

Full description

Saved in:
Bibliographic Details
Published in:Russian journal of organic chemistry 2017-03, Vol.53 (3), p.413-417
Main Authors: Yarosh, N. O., Zhilitskaya, L. V., Shagun, L. G., Dorofeev, I. A., Larina, L. I.
Format: Article
Language:English
Subjects:
Alkylation
Chemical synthesis
Chemistry
Chemistry and Materials Science
Imidazole
Organic Chemistry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:2-Methyl-1,3-bis[(1-methylsilolan-1-yl)methyl]-1 H -imidazolium triiodide, 1,3-bis{[dimethyl-(phenyl)silyl]methyl}-2-methyl-1 H -imidazolium iodide and triiodide, and cyclic 3,3,5,5,10-pentamethyl-4-oxa-7-aza-1-azonia-3,5-disilabicyclo[5.2.1]deca-1(10),8-diene iodide were synthesized by solvent-free reactions of 2-methyl-1 H -imidazole with 1-(iodomethyl)-1-methylsilolane, (iodomethyl)(dimethyl)phenylsilane, and ethynyl(iodomethyl)(dimethyl)silanes, respectively, in the absence of base catalyst.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428017030162