Oligomerization of higher olefins and alkylation of toluene catalyzed by 2-[hydroxy(diaryl)methyl]-8-hydroxyquinoline oxovanadium(v) complexes

New oxovanadium(V) complexes with 2-[hydroxy(diaryl)methyl]-8-hydroxyquinoline ligands were synthesized. These compounds were found to be efficient tandem catalysts of oligomerization of hex-1-ene and alkylation of toluene, which leads to the mixture of hexyl-, dihexyl-, and trihexyltoluenes with th...

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Bibliographic Details
Published in:Russian chemical bulletin 2016-11, Vol.65 (11), p.2757-2759
Main Authors: Kolosov, N. A., Tuskaev, V. A., Gagieva, S. Ch, Polyakova, O. V., Sizov, A. I., Bulychev, B. M.
Format: Article
Language:English
Subjects:
Alkenes
Alkylation
Brief Communications
Chemical synthesis
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Hydroxyquinoline
Inorganic Chemistry
Oligomerization
Organic Chemistry
Toluene
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Summary:New oxovanadium(V) complexes with 2-[hydroxy(diaryl)methyl]-8-hydroxyquinoline ligands were synthesized. These compounds were found to be efficient tandem catalysts of oligomerization of hex-1-ene and alkylation of toluene, which leads to the mixture of hexyl-, dihexyl-, and trihexyltoluenes with the conversion of the starting alkene more than 99%.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-016-1648-9