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Mechanism of MxOy nanoparticles/CNTs for catalytic carbonization of polyethylene and application to flame retardancy

ABSTRACT Three kinds of metal oxide nanoparticles (Fe3O4, Co3O4, and Ni2O3) are produced on carbon nanotubes (CNTs). The synergistic effects rendered by the CNTs and metal oxide nanoparticles on carbonization of polyethylene (PE) are studied and applications to flame retardancy of PE are investigate...

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Published in:	Journal of applied polymer science 2017-09, Vol.134 (34), p.n/a
Main Authors:	Wenelska, Karolina, Chen, Xuecheng, Zielinska, Beata, Kaleńczuk, Ryszard J., Chu, Paul K., Tang, Tao, Mijowska, Ewa
Format:	Article
Language:	English
Subjects:	carbon nanotube Carbon nanotubes Carbonation Carbonization Catalysis Cobalt oxides flame retardant Iron Materials science metal oxide Metal oxides Nanoparticles Nickel Polyethylene Polyethylenes Polymers Wood products
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container_title	Journal of applied polymer science
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creator	Wenelska, Karolina Chen, Xuecheng Zielinska, Beata Kaleńczuk, Ryszard J. Chu, Paul K. Tang, Tao Mijowska, Ewa
description	ABSTRACT Three kinds of metal oxide nanoparticles (Fe3O4, Co3O4, and Ni2O3) are produced on carbon nanotubes (CNTs). The synergistic effects rendered by the CNTs and metal oxide nanoparticles on carbonization of polyethylene (PE) are studied and applications to flame retardancy of PE are investigated systematically. The CNT‐Ni2O3 delivers the best performance and the mechanism pertaining to the enhanced flame retardancy is proposed and discussed. It is found that under the same conditions, the carbonization rate can be a factor to influence the flame retardancy performance. Among Fe, Co, and Ni, Ni has the fastest carbonation rate, which leads to the best flame retardancy performance. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 45233.
doi_str_mv	10.1002/app.45233
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subjects	carbon nanotube Carbon nanotubes Carbonation Carbonization Catalysis Cobalt oxides flame retardant Iron Materials science metal oxide Metal oxides Nanoparticles Nickel Polyethylene Polyethylenes Polymers Wood products
title	Mechanism of MxOy nanoparticles/CNTs for catalytic carbonization of polyethylene and application to flame retardancy
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