Synthesis of ethyl (2E,4E)- and (2E,4Z)-5-chloropenta-2,4-dienoates

An efficient synthetic approach to 2 E ,4 E and 2 E ,4 Z isomers of ethyl 5-chloropenta-2,4-dienoate has been developed on the basis of one-pot oxidation–olefination of readily accessible ( E )- and ( Z )-3-chloroprop-2-en-1-ols by the action of barium manganate and ethyl (triphenyl-λ 5 -phosphanyli...

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Bibliographic Details
Published in:Russian journal of organic chemistry 2017, Vol.53 (4), p.615-617
Main Authors: Shakhmaev, R. N., Sunagatullina, A. Sh, Akimova, D. A., Zorin, V. V.
Format: Article
Language:English
Subjects:
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Chemistry
Chemistry and Materials Science
Isomers
Organic Chemistry
Oxidation
Short Communications
Synthesis
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Summary:An efficient synthetic approach to 2 E ,4 E and 2 E ,4 Z isomers of ethyl 5-chloropenta-2,4-dienoate has been developed on the basis of one-pot oxidation–olefination of readily accessible ( E )- and ( Z )-3-chloroprop-2-en-1-ols by the action of barium manganate and ethyl (triphenyl-λ 5 -phosphanylidene)acetate.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428017040194