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Selective Dinitrogen Conversion to Ammonia Using Water and Visible Light through Plasmon-induced Charge Separation
The generation of ammonia from atmospheric nitrogen and water using sunlight is a preferable approach to obtaining ammonia as an energy carrier and potentially represents a new paradigm for achieving a low‐carbon and sustainable‐energy society. Herein, we report the selective conversion of dinitroge...
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Published in: | Angewandte Chemie International Edition 2016-03, Vol.55 (12), p.3942-3946 |
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creator | Oshikiri, Tomoya Ueno, Kosei Misawa, Hiroaki |
description | The generation of ammonia from atmospheric nitrogen and water using sunlight is a preferable approach to obtaining ammonia as an energy carrier and potentially represents a new paradigm for achieving a low‐carbon and sustainable‐energy society. Herein, we report the selective conversion of dinitrogen into ammonia through plasmon‐induced charge separation by using a strontium titanate (SrTiO3) photoelectrode loaded with gold nanoparticles (Au‐NPs) and a zirconium/zirconium oxide (Zr/ZrOx) thin film. We observed the simultaneous stoichiometric production of ammonia and oxygen from nitrogen and water under visible‐light irradiation.
NH3 sees the light of day: A highly selective and visible‐light‐responsive plasmonic NH3 synthesis device containing a Au nanostructure and a Zr/ZrOx thin film was developed. N2 gas was reduced to NH3 by using water as an electron donor through plasmon‐induced charge separation under visible light irradiation. |
doi_str_mv | 10.1002/anie.201511189 |
format | article |
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NH3 sees the light of day: A highly selective and visible‐light‐responsive plasmonic NH3 synthesis device containing a Au nanostructure and a Zr/ZrOx thin film was developed. N2 gas was reduced to NH3 by using water as an electron donor through plasmon‐induced charge separation under visible light irradiation.</description><edition>International ed. in English</edition><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.201511189</identifier><identifier>PMID: 26890286</identifier><identifier>CODEN: ACIEAY</identifier><language>eng</language><publisher>Germany: Blackwell Publishing Ltd</publisher><subject>Ammonia ; Carbon ; Conversion ; Direct power generation ; Energy ; Energy consumption ; Gold ; Irradiation ; Light effects ; Light irradiation ; localized surface plasmon ; Nanoparticles ; nanostructures ; Nitrogen ; nitrogen fixation ; Oxygen ; photochemistry ; Radiation ; Renewable energy ; Separation ; Strontium ; Strontium titanates ; Sunlight ; Zirconium ; Zirconium oxides</subject><ispartof>Angewandte Chemie International Edition, 2016-03, Vol.55 (12), p.3942-3946</ispartof><rights>2016 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.</rights><rights>2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c6829-df12553e333d57eac2f90f65d2e5724f2915b75bd54512794e55ab13b8338ed23</citedby><cites>FETCH-LOGICAL-c6829-df12553e333d57eac2f90f65d2e5724f2915b75bd54512794e55ab13b8338ed23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/26890286$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Oshikiri, Tomoya</creatorcontrib><creatorcontrib>Ueno, Kosei</creatorcontrib><creatorcontrib>Misawa, Hiroaki</creatorcontrib><title>Selective Dinitrogen Conversion to Ammonia Using Water and Visible Light through Plasmon-induced Charge Separation</title><title>Angewandte Chemie International Edition</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>The generation of ammonia from atmospheric nitrogen and water using sunlight is a preferable approach to obtaining ammonia as an energy carrier and potentially represents a new paradigm for achieving a low‐carbon and sustainable‐energy society. Herein, we report the selective conversion of dinitrogen into ammonia through plasmon‐induced charge separation by using a strontium titanate (SrTiO3) photoelectrode loaded with gold nanoparticles (Au‐NPs) and a zirconium/zirconium oxide (Zr/ZrOx) thin film. We observed the simultaneous stoichiometric production of ammonia and oxygen from nitrogen and water under visible‐light irradiation.
NH3 sees the light of day: A highly selective and visible‐light‐responsive plasmonic NH3 synthesis device containing a Au nanostructure and a Zr/ZrOx thin film was developed. N2 gas was reduced to NH3 by using water as an electron donor through plasmon‐induced charge separation under visible light irradiation.</description><subject>Ammonia</subject><subject>Carbon</subject><subject>Conversion</subject><subject>Direct power generation</subject><subject>Energy</subject><subject>Energy consumption</subject><subject>Gold</subject><subject>Irradiation</subject><subject>Light effects</subject><subject>Light irradiation</subject><subject>localized surface plasmon</subject><subject>Nanoparticles</subject><subject>nanostructures</subject><subject>Nitrogen</subject><subject>nitrogen fixation</subject><subject>Oxygen</subject><subject>photochemistry</subject><subject>Radiation</subject><subject>Renewable energy</subject><subject>Separation</subject><subject>Strontium</subject><subject>Strontium titanates</subject><subject>Sunlight</subject><subject>Zirconium</subject><subject>Zirconium oxides</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNqFkU1P3DAQhiNUVCj0yrGy1HO2_sjYyXGVUkBaUSpgOVpOPMmaZp3FTmj5981q6aonevJYet5npHmT5IzRGaOUfzHe4YxTBoyxvDhIjhlwlgqlxLtpzoRIVQ7sKPkQ4-PE5zmV75MjLvNi-sjjJNxih_XgnpF8dd4NoW_Rk7L3zxii6z0ZejJfr3vvDLmPzrfkwQwYiPGWLF10VYdk4drVQIZV6Md2RW46Eyc-dd6ONVpSrkxokdzixgQzTMrT5LAxXcSPr-9Jcv_t_K68TBffL67K-SKtZc6L1DaMAwgUQlhQaGreFLSRYDmC4lnDCwaVgspCBoyrIkMAUzFR5ULkaLk4ST7vvJvQP40YB_3Yj8FPKzUrqJQZUAVvUkpxEBnILTXbUXXoYwzY6E1waxNeNKN6W4TeFqH3RUyBT6_asVqj3eN_Lz8BxQ745Tp8-Y9Oz6-vzv-Vp7usiwP-3mdN-KmlEgr0w_WFXi6yH0t2Weob8Qe7BaNf</recordid><startdate>20160314</startdate><enddate>20160314</enddate><creator>Oshikiri, Tomoya</creator><creator>Ueno, Kosei</creator><creator>Misawa, Hiroaki</creator><general>Blackwell Publishing Ltd</general><general>Wiley Subscription Services, Inc</general><scope>BSCLL</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7TM</scope><scope>K9.</scope></search><sort><creationdate>20160314</creationdate><title>Selective Dinitrogen Conversion to Ammonia Using Water and Visible Light through Plasmon-induced Charge Separation</title><author>Oshikiri, Tomoya ; Ueno, Kosei ; Misawa, Hiroaki</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c6829-df12553e333d57eac2f90f65d2e5724f2915b75bd54512794e55ab13b8338ed23</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Ammonia</topic><topic>Carbon</topic><topic>Conversion</topic><topic>Direct power generation</topic><topic>Energy</topic><topic>Energy consumption</topic><topic>Gold</topic><topic>Irradiation</topic><topic>Light effects</topic><topic>Light irradiation</topic><topic>localized surface plasmon</topic><topic>Nanoparticles</topic><topic>nanostructures</topic><topic>Nitrogen</topic><topic>nitrogen fixation</topic><topic>Oxygen</topic><topic>photochemistry</topic><topic>Radiation</topic><topic>Renewable energy</topic><topic>Separation</topic><topic>Strontium</topic><topic>Strontium titanates</topic><topic>Sunlight</topic><topic>Zirconium</topic><topic>Zirconium oxides</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Oshikiri, Tomoya</creatorcontrib><creatorcontrib>Ueno, Kosei</creatorcontrib><creatorcontrib>Misawa, Hiroaki</creatorcontrib><collection>Istex</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>Nucleic Acids Abstracts</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><jtitle>Angewandte Chemie International Edition</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Oshikiri, Tomoya</au><au>Ueno, Kosei</au><au>Misawa, Hiroaki</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Selective Dinitrogen Conversion to Ammonia Using Water and Visible Light through Plasmon-induced Charge Separation</atitle><jtitle>Angewandte Chemie International Edition</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2016-03-14</date><risdate>2016</risdate><volume>55</volume><issue>12</issue><spage>3942</spage><epage>3946</epage><pages>3942-3946</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><coden>ACIEAY</coden><abstract>The generation of ammonia from atmospheric nitrogen and water using sunlight is a preferable approach to obtaining ammonia as an energy carrier and potentially represents a new paradigm for achieving a low‐carbon and sustainable‐energy society. Herein, we report the selective conversion of dinitrogen into ammonia through plasmon‐induced charge separation by using a strontium titanate (SrTiO3) photoelectrode loaded with gold nanoparticles (Au‐NPs) and a zirconium/zirconium oxide (Zr/ZrOx) thin film. We observed the simultaneous stoichiometric production of ammonia and oxygen from nitrogen and water under visible‐light irradiation.
NH3 sees the light of day: A highly selective and visible‐light‐responsive plasmonic NH3 synthesis device containing a Au nanostructure and a Zr/ZrOx thin film was developed. N2 gas was reduced to NH3 by using water as an electron donor through plasmon‐induced charge separation under visible light irradiation.</abstract><cop>Germany</cop><pub>Blackwell Publishing Ltd</pub><pmid>26890286</pmid><doi>10.1002/anie.201511189</doi><tpages>5</tpages><edition>International ed. in English</edition></addata></record> |
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subjects | Ammonia Carbon Conversion Direct power generation Energy Energy consumption Gold Irradiation Light effects Light irradiation localized surface plasmon Nanoparticles nanostructures Nitrogen nitrogen fixation Oxygen photochemistry Radiation Renewable energy Separation Strontium Strontium titanates Sunlight Zirconium Zirconium oxides |
title | Selective Dinitrogen Conversion to Ammonia Using Water and Visible Light through Plasmon-induced Charge Separation |
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