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S- and Sr-isotopic compositions in barite–silica chimney from the Franklin Seamount, Woodlark Basin, Papua New Guinea: constraints on genesis and temporal variability of hydrothermal fluid

Isotopic ratios of strontium and sulfur in six layers across a horizontal section of a hydrothermal barite–silica chimney from Franklin Seamount of western Woodlark Basin have been investigated. Sr-isotopic ratios in barite samples ( 87 Sr/ 86 Sr = 0.70478–0.70493) are less radiogenic than seawater...

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Published in:International journal of earth sciences : Geologische Rundschau 2017-07, Vol.106 (5), p.1723-1733
Main Authors: Ray, Durbar, Banerjee, Ranadip, Balakrishnan, S., Paropkari, Anil L., Mukhopadhyay, Subir
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container_title International journal of earth sciences : Geologische Rundschau
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description Isotopic ratios of strontium and sulfur in six layers across a horizontal section of a hydrothermal barite–silica chimney from Franklin Seamount of western Woodlark Basin have been investigated. Sr-isotopic ratios in barite samples ( 87 Sr/ 86 Sr = 0.70478–0.70493) are less radiogenic than seawater ( 87 Sr/ 86 Sr = 0.70917) indicating that substantial leaching of sub-seafloor magma was involved in the genesis of hydrothermal fluid. The SO 2 of magma likely contributed a considerable amount of lighter S-isotope in fluid and responsible for the formation of barite, which is isotopically lighter (δ 34 S = 19.4–20.5 ‰) than modern seawater (δ 34 S ~ 21 ‰). The systematic changes in isotopic compositions across the chimney wall suggest temporal changes in the mode of mineral formation during the growth of the chimney. Enrichment of heavy S- and Sr-isotopes (δ 34 S = 20.58 ‰; 87 Sr/ 86 Sr = 0.70493) in the outermost periphery of the chimney indicates that, at the initial stage of chimney development, there was a significant contribution of seawater sulfate during barite mineralization. Thereafter, thickening of chimney wall occurred due to precipitation of fluid carrying more magmatic components relative to seawater. This led to a gradual enrichment of lighter isotopes (δ 34 S = 20.42–19.48 ‰; 87 Sr/ 86 Sr = 0.70491–0.704787) toward the inner portion of the chimney wall. In contrast, the innermost layer surrounding the fluid conduit is characterized by heavier and more radiogenic isotopes (δ 34 S = 20.3 ‰; 87 Sr/ 86 Sr = 0.7049). This suggests there was increasing influence of percolating seawater on the mineral paragenesis at the waning phase of the chimney development.
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subjects Atmospheric precipitations
Barite
Basins
Chemical analysis
Components
Earth and Environmental Science
Earth Sciences
Enrichment
Geochemistry
Geology
Geophysics/Geodesy
Growth
Hydrologic cycle
Isotope composition
Isotopes
Lava
Leaching
Magma
Mineral Resources
Mineralization
Ocean floor
Original Paper
Precipitation
Ratios
Seamounts
Seawater
Sedimentology
Silica
Silicon dioxide
Strontium
Strontium isotopes
Structural Geology
Sulfur
Sulfur dioxide
Sulphur
Temporal variability
Temporal variations
Thermal energy
Thickening
Variability
Water analysis
title S- and Sr-isotopic compositions in barite–silica chimney from the Franklin Seamount, Woodlark Basin, Papua New Guinea: constraints on genesis and temporal variability of hydrothermal fluid
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