Study of the reactivity of organonickel sigma-complexes towards nitriles

The reactivity of organonickel sigma-complexes of type [NiBr(Ar)(bpy)], where Ar = 2,6-dimethylphenyl (Xyl), 2,4,6-trimethylphenyl (Mes), 2,4,6-triisopropylphenyl (Tipp), 2,4,6-tricyclohexylphenyl (Tchp), bpy = 2,2´-bipyridine, towards nitriles (acetonitrile, propionitrile, chloroacetonitrile, benzo...

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Bibliographic Details
Published in:Russian chemical bulletin 2017-02, Vol.66 (2), p.254-259
Main Authors: Gafurov, Z. N., Sakhapov, I. F., Babaev, V. M., Dobrynin, A. B., Kurmaz, V. A., Metlushka, K. E., Rizvanov, I. Kh, Shaikhutdinova, G. R., Sinyashin, O. G., Yakhvarov, D. G.
Format: Article
Language:English
Subjects:
Acetonitrile
Benzonitrile
Carbon
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
Fragmentation
Full Articles
Imines
Inorganic Chemistry
Nitriles
Organic Chemistry
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Summary:The reactivity of organonickel sigma-complexes of type [NiBr(Ar)(bpy)], where Ar = 2,6-dimethylphenyl (Xyl), 2,4,6-trimethylphenyl (Mes), 2,4,6-triisopropylphenyl (Tipp), 2,4,6-tricyclohexylphenyl (Tchp), bpy = 2,2´-bipyridine, towards nitriles (acetonitrile, propionitrile, chloroacetonitrile, benzonitrile) has been investigated. This reaction leads to imines by formation of new carbon—carbon bond between aromatic fragment and nitrile group C≡N.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-017-1725-8