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Orthogonal and Collinear Configurations in Double-Pulse Laser-Induced Breakdown Spectrometry to Improve Sensitivity in Chlorine Determination

We consider collinear and orthogonal beam-convergence configurations in double-pulse laser-induced breakdown spectrometry (LIBS, also known as laser-spark emission spectrometry) for chlorine determination in plants and concrete from the Cl I 837.59 nm line. We have observed that the signal-to-noise...

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Published in:	Journal of applied spectroscopy 2017-05, Vol.84 (2), p.319-323
Main Authors:	Zakuskin, A. S., Popov, A. M., Zaytsev, S. M., Zorov, N. B., Belkov, M. V., Labutin, T. A.
Format:	Article
Language:	English
Subjects:	Analysis Analytical Chemistry Atomic/Molecular Structure and Spectra Chlorine Laser beams Laser induced breakdown Lasers Physics Physics and Astronomy Scientific imaging Sensitivity Signal to noise ratio Spectrometry Spectroscopy Stability
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container_title	Journal of applied spectroscopy
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description	We consider collinear and orthogonal beam-convergence configurations in double-pulse laser-induced breakdown spectrometry (LIBS, also known as laser-spark emission spectrometry) for chlorine determination in plants and concrete from the Cl I 837.59 nm line. We have observed that the signal-to-noise ratio is not much lower for the orthogonal configuration due to spatial instability in the second breakdown. At the same time, suppression of interfering molecular bands in this configuration lets us improve the sensitivity of LIBS for chlorine determination in plant material.
doi_str_mv	10.1007/s10812-017-0470-y
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subjects	Analysis Analytical Chemistry Atomic/Molecular Structure and Spectra Chlorine Laser beams Laser induced breakdown Lasers Physics Physics and Astronomy Scientific imaging Sensitivity Signal to noise ratio Spectrometry Spectroscopy Stability
title	Orthogonal and Collinear Configurations in Double-Pulse Laser-Induced Breakdown Spectrometry to Improve Sensitivity in Chlorine Determination
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