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The Porous Structure Characterization of Products of Non-Equilibrium Electrochemical Oxidation of Copper and Cadmium
The porous structure of copper-cadmium oxide system produced by electrochemical synthesis using alternating current in ammonium chloride solutions with concentrations of 3 and 25 wt% was studied. It was shown that the composition of electrolysis products is represented by oxides of copper (I) and (I...
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Published in: | Key engineering materials 2017-07, Vol.743, p.292-296 |
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creator | Korobochkin, Valery Popov, Maksim Usoltseva, Natalya Popova, Evgeniya Frolova, Irina Kozik, Vladimir Dolinina, Alesya |
description | The porous structure of copper-cadmium oxide system produced by electrochemical synthesis using alternating current in ammonium chloride solutions with concentrations of 3 and 25 wt% was studied. It was shown that the composition of electrolysis products is represented by oxides of copper (I) and (II), hydroxides of cadmium; it depends on the current density and the solution concentration. The products of joint electrochemical oxidation of copper and cadmium obtained in ammonium chloride solution with concentrations of 3 and 25 wt% and current densities of 1 and 3 A/cm2 are characterized by mesoporous structure. |
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It was shown that the composition of electrolysis products is represented by oxides of copper (I) and (II), hydroxides of cadmium; it depends on the current density and the solution concentration. The products of joint electrochemical oxidation of copper and cadmium obtained in ammonium chloride solution with concentrations of 3 and 25 wt% and current densities of 1 and 3 A/cm2 are characterized by mesoporous structure.</description><identifier>ISSN: 1013-9826</identifier><identifier>ISSN: 1662-9795</identifier><identifier>EISSN: 1662-9795</identifier><identifier>DOI: 10.4028/www.scientific.net/KEM.743.292</identifier><language>eng</language><publisher>Zurich: Trans Tech Publications Ltd</publisher><subject>Alternating current ; Cadmium ; Chlorides ; Concentration (composition) ; Copper ; Current density ; Electrochemical oxidation ; Electrolysis ; Hydroxides ; Oxidation ; Oxides ; Structural analysis</subject><ispartof>Key engineering materials, 2017-07, Vol.743, p.292-296</ispartof><rights>2017 Trans Tech Publications Ltd</rights><rights>Copyright Trans Tech Publications Ltd. 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subjects | Alternating current Cadmium Chlorides Concentration (composition) Copper Current density Electrochemical oxidation Electrolysis Hydroxides Oxidation Oxides Structural analysis |
title | The Porous Structure Characterization of Products of Non-Equilibrium Electrochemical Oxidation of Copper and Cadmium |
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