Easy Access to SCF2‐Containing Molecules through a Versatile Reagent

A new fluoroalkylmethanesulfenamide reagent was developed to synthesize various molecules bearing the SCF2CO2Me group. Furthermore, the carboxyl function was successfully post‐transformed, through C–C coupling, for easy access to molecules containing the –SCF2– functionality. A fluoroalkylmethanesul...

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Bibliographic Details
Published in:European journal of organic chemistry 2017-04, Vol.2017 (14), p.1911-1914
Main Authors: Ismalaj, Ermal, Glenadel, Quentin, Billard, Thierry
Format: Article
Language:English
Subjects:
Aromatic substitution
Carbonyl compounds
Chemical synthesis
Coupling (molecular)
C–C coupling
Fluorine
Group dynamics
Sulfur
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Summary:A new fluoroalkylmethanesulfenamide reagent was developed to synthesize various molecules bearing the SCF2CO2Me group. Furthermore, the carboxyl function was successfully post‐transformed, through C–C coupling, for easy access to molecules containing the –SCF2– functionality. A fluoroalkylmethanesulfenamide reagent was developed to synthesize various molecules bearing the SCF2CO2Me group. Furthermore, the carboxyl function is successfully post‐transformed, through C–C coupling, for easy access to molecules containing the –SCF2– functionality.
ISSN:1434-193X
1099-0690
DOI:10.1002/ejoc.201700103