(Pentamethylcyclopentadienyl)cobalt(III)‐Catalyzed Direct Trifluoromethylthiolation of Arenes via C−H Activation

The direct trifluoromethylthiolation of arenes was realized via (pentamethylcyclopentadienyl)cobalt(III)‐catalyzed C(sp2)‐H activation and coupling with AgSCF3 under the assistance of a directing group. The reaction features redox‐neutrality, mild conditions, broad substrate scope, and good function...

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Bibliographic Details
Published in:Advanced synthesis & catalysis 2017-06, Vol.359 (11), p.1942-1946
Main Authors: Liu, Xu‐Ge, Li, Qingjiang, Wang, Honggen
Format: Article
Language:English
Subjects:
Activation
arene trifluoromethylthiolation
Aromatic compounds
Cobalt
C−H activation
silver
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Summary:The direct trifluoromethylthiolation of arenes was realized via (pentamethylcyclopentadienyl)cobalt(III)‐catalyzed C(sp2)‐H activation and coupling with AgSCF3 under the assistance of a directing group. The reaction features redox‐neutrality, mild conditions, broad substrate scope, and good functional group tolerance. Preliminary mechanistic studies have been conducted.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.201700066