Back Cover: CuI/Oxalic Diamide‐Catalyzed Cross‐Coupling of Thiols with Aryl Bromides and Chlorides (Chem. Eur. J. 42/2017)

A practical synthetic method for the synthesis of diversified thioethers using oxalic diamides as highly air‐stable ligands through copper catalysis is demonstrated. A variety of aryl and alkyl thiols were successfully coupled with aryl bromides and aryl chlorides to afford the corresponding thioeth...

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Bibliographic Details
Published in:Chemistry : a European journal 2017-07, Vol.23 (42), p.10231-10231
Main Authors: Chen, Chia‐Wei, Chen, Yi‐Ling, Reddy, Daggula Mallikarjuna, Du, Kai, Li, Chao‐En, Shih, Bo‐Hao, Xue, Yung‐Jing, Lee, Chin‐Fa
Format: Article
Language:English
Subjects:
Aromatic compounds
aryl halides
Bromides
Catalysis
Chemistry
Chlorides
Copper
Cross coupling
oxalic diamides
Thioethers
Thiols
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Summary:A practical synthetic method for the synthesis of diversified thioethers using oxalic diamides as highly air‐stable ligands through copper catalysis is demonstrated. A variety of aryl and alkyl thiols were successfully coupled with aryl bromides and aryl chlorides to afford the corresponding thioethers in good yields. This work is the first copper‐catalyzed thioetherification of unactivated aryl chlorides. More information can be found in the Full Paper by C.‐F. Lee et al. on page 10087.
ISSN:0947-6539
1521-3765
DOI:10.1002/chem.201702327