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Chemistry of iminofurans: XIV. Ring opening of 5-substituted furan-2,3-dione 3-benzoylhydrazones by the action of aromatic and heterocyclic amines

Reactions of 5-aryl- and 5- tert -butyl-3-(benzoylhydrazinylidene)furan-2,3-diones with aromatic and heterocyclic amines afforded 4-aryl-2-(benzoylhydrazinylidene)-4-oxobutanamides and 5,5-dimethyl-2-(benzoylhydrazinylidene)-4-oxohexanamides which exist in solution as mixtures of hydrazone and cycli...

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Published in:Russian journal of organic chemistry 2017-06, Vol.53 (6), p.920-925
Main Authors: Kiselev, M. A., Igidov, N. M., Chernov, I. N., Toksarova, Yu. S., Rubtsov, A. E.
Format: Article
Language:English
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Summary:Reactions of 5-aryl- and 5- tert -butyl-3-(benzoylhydrazinylidene)furan-2,3-diones with aromatic and heterocyclic amines afforded 4-aryl-2-(benzoylhydrazinylidene)-4-oxobutanamides and 5,5-dimethyl-2-(benzoylhydrazinylidene)-4-oxohexanamides which exist in solution as mixtures of hydrazone and cyclic dihydropyrazole tautomers.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428017060173