Kinetics of a bimolecular chemical reaction in the liquid phase with association of both reactants

Mathematical modeling of a bimolecular chemical reaction in the liquid phase was carried out taking account of association of both reactants. The formally simple chemical reaction is thus transformed into a multistage process, which results in the formation of temporal dissipative structures. It was...

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Bibliographic Details
Published in:Doklady. Physical chemistry (1991) 2017-07, Vol.475 (1), p.126-128
Main Authors: Kulagina, T. P., Smirnov, L. P., Andrianova, Z. S.
Format: Article
Language:English
Subjects:
Chemical reactions
Chemistry
Chemistry and Materials Science
Dissipation
Physical Chemistry
Product design
Reaction kinetics
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Summary:Mathematical modeling of a bimolecular chemical reaction in the liquid phase was carried out taking account of association of both reactants. The formally simple chemical reaction is thus transformed into a multistage process, which results in the formation of temporal dissipative structures. It was found that, apart from the usual dynamic modes, there appear oscillations of the concentrations of intermediates, characterized by two considerably differing periods.
ISSN:0012-5016
1608-3121
DOI:10.1134/S0012501617070065