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High-temperature heat content and thermodynamic functions of REEuTi2O7 (RE = Gd, Dy) from calorimetric measurements
Titanates of gadolinium, europium, and dysprosium are considered potential candidate materials for use in the control rods of future nuclear reactors. GdEuTi 2 O 7 and DyEuTi 2 O 7 were synthesized by powder-pellet route and were characterized by using X-ray diffraction technique. Enthalpy increment...
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| Published in: | Journal of thermal analysis and calorimetry 2017-09, Vol.129 (3), p.1563-1572 |
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| Main Authors: | , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c353t-c794030bc268b0c82bab0bd25470653dbc4e5a31fd322e29103cc1981ec37ee43 |
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| cites | cdi_FETCH-LOGICAL-c353t-c794030bc268b0c82bab0bd25470653dbc4e5a31fd322e29103cc1981ec37ee43 |
| container_end_page | 1572 |
| container_issue | 3 |
| container_start_page | 1563 |
| container_title | Journal of thermal analysis and calorimetry |
| container_volume | 129 |
| creator | Kandan, R. Panneerselvam, G. Prabhakara Reddy, B. |
| description | Titanates of gadolinium, europium, and dysprosium are considered potential candidate materials for use in the control rods of future nuclear reactors. GdEuTi
2
O
7
and DyEuTi
2
O
7
were synthesized by powder-pellet route and were characterized by using X-ray diffraction technique. Enthalpy increment measurements were carried out on these compounds in temperature range 795–1658 K by inverse drop calorimetric method by using a high-temperature differential calorimeter. Thermodynamic functions such as heat capacity, entropy, and Gibbs energy functions in the temperature range 298–1700 K were computed from the measured enthalpy increments. |
| doi_str_mv | 10.1007/s10973-017-6216-5 |
| format | article |
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2
O
7
and DyEuTi
2
O
7
were synthesized by powder-pellet route and were characterized by using X-ray diffraction technique. Enthalpy increment measurements were carried out on these compounds in temperature range 795–1658 K by inverse drop calorimetric method by using a high-temperature differential calorimeter. Thermodynamic functions such as heat capacity, entropy, and Gibbs energy functions in the temperature range 298–1700 K were computed from the measured enthalpy increments.</description><identifier>ISSN: 1388-6150</identifier><identifier>EISSN: 1588-2926</identifier><identifier>DOI: 10.1007/s10973-017-6216-5</identifier><language>eng</language><publisher>Dordrecht: Springer Netherlands</publisher><subject>Analytical Chemistry ; Chemistry ; Chemistry and Materials Science ; Control rods ; Dysprosium ; Enthalpy ; Europium ; Gadolinium ; Heat measurement ; Inorganic Chemistry ; Materials selection ; Measurement Science and Instrumentation ; Nuclear energy ; Nuclear reactors ; Physical Chemistry ; Polymer Sciences ; Specific heat ; Titanates ; X-ray diffraction</subject><ispartof>Journal of thermal analysis and calorimetry, 2017-09, Vol.129 (3), p.1563-1572</ispartof><rights>Akadémiai Kiadó, Budapest, Hungary 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c353t-c794030bc268b0c82bab0bd25470653dbc4e5a31fd322e29103cc1981ec37ee43</citedby><cites>FETCH-LOGICAL-c353t-c794030bc268b0c82bab0bd25470653dbc4e5a31fd322e29103cc1981ec37ee43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail></links><search><creatorcontrib>Kandan, R.</creatorcontrib><creatorcontrib>Panneerselvam, G.</creatorcontrib><creatorcontrib>Prabhakara Reddy, B.</creatorcontrib><title>High-temperature heat content and thermodynamic functions of REEuTi2O7 (RE = Gd, Dy) from calorimetric measurements</title><title>Journal of thermal analysis and calorimetry</title><addtitle>J Therm Anal Calorim</addtitle><description>Titanates of gadolinium, europium, and dysprosium are considered potential candidate materials for use in the control rods of future nuclear reactors. GdEuTi
2
O
7
and DyEuTi
2
O
7
were synthesized by powder-pellet route and were characterized by using X-ray diffraction technique. Enthalpy increment measurements were carried out on these compounds in temperature range 795–1658 K by inverse drop calorimetric method by using a high-temperature differential calorimeter. Thermodynamic functions such as heat capacity, entropy, and Gibbs energy functions in the temperature range 298–1700 K were computed from the measured enthalpy increments.</description><subject>Analytical Chemistry</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Control rods</subject><subject>Dysprosium</subject><subject>Enthalpy</subject><subject>Europium</subject><subject>Gadolinium</subject><subject>Heat measurement</subject><subject>Inorganic Chemistry</subject><subject>Materials selection</subject><subject>Measurement Science and Instrumentation</subject><subject>Nuclear energy</subject><subject>Nuclear reactors</subject><subject>Physical Chemistry</subject><subject>Polymer Sciences</subject><subject>Specific heat</subject><subject>Titanates</subject><subject>X-ray diffraction</subject><issn>1388-6150</issn><issn>1588-2926</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kLtOxDAQRSMEErDwAXSWaEAiMGPnWVCgJTyklZAQ1JbjTNisNvFiO8X-zX4LX4ZRKGioZop77oxOFJ0hXCNAfuMQylzEgHmccczidC86wrQoYl7ybD_sIuwZpnAYHTu3AoCyBDyKxqfuYxl76jdklR8tsSUpz7QZPA2eqaFhfkm2N812UH2nWTsO2ndmcMy07LWqxreOv-Ts4rX62t1-7R6bK3a_vWStNT3Tam1s15O3AexJudDfh1p3Eh20au3o9HfOoveH6m3-FC9eHp_nd4tYi1T4WOdlAgJqzbOiBl3wWtVQNzxNcshS0dQ6oVQJbBvBOfESQWiNZYGkRU6UiFl0PvVurPkcyXm5MqMdwkmJwQvmiEkWUjiltDXOWWrlJnyt7FYiyB-7crIrg135Y1emgeET40J2-CD7p_lf6BuKF35H</recordid><startdate>20170901</startdate><enddate>20170901</enddate><creator>Kandan, R.</creator><creator>Panneerselvam, G.</creator><creator>Prabhakara Reddy, B.</creator><general>Springer Netherlands</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170901</creationdate><title>High-temperature heat content and thermodynamic functions of REEuTi2O7 (RE = Gd, Dy) from calorimetric measurements</title><author>Kandan, R. ; Panneerselvam, G. ; Prabhakara Reddy, B.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c353t-c794030bc268b0c82bab0bd25470653dbc4e5a31fd322e29103cc1981ec37ee43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Analytical Chemistry</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Control rods</topic><topic>Dysprosium</topic><topic>Enthalpy</topic><topic>Europium</topic><topic>Gadolinium</topic><topic>Heat measurement</topic><topic>Inorganic Chemistry</topic><topic>Materials selection</topic><topic>Measurement Science and Instrumentation</topic><topic>Nuclear energy</topic><topic>Nuclear reactors</topic><topic>Physical Chemistry</topic><topic>Polymer Sciences</topic><topic>Specific heat</topic><topic>Titanates</topic><topic>X-ray diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kandan, R.</creatorcontrib><creatorcontrib>Panneerselvam, G.</creatorcontrib><creatorcontrib>Prabhakara Reddy, B.</creatorcontrib><collection>CrossRef</collection><jtitle>Journal of thermal analysis and calorimetry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kandan, R.</au><au>Panneerselvam, G.</au><au>Prabhakara Reddy, B.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>High-temperature heat content and thermodynamic functions of REEuTi2O7 (RE = Gd, Dy) from calorimetric measurements</atitle><jtitle>Journal of thermal analysis and calorimetry</jtitle><stitle>J Therm Anal Calorim</stitle><date>2017-09-01</date><risdate>2017</risdate><volume>129</volume><issue>3</issue><spage>1563</spage><epage>1572</epage><pages>1563-1572</pages><issn>1388-6150</issn><eissn>1588-2926</eissn><abstract>Titanates of gadolinium, europium, and dysprosium are considered potential candidate materials for use in the control rods of future nuclear reactors. GdEuTi
2
O
7
and DyEuTi
2
O
7
were synthesized by powder-pellet route and were characterized by using X-ray diffraction technique. Enthalpy increment measurements were carried out on these compounds in temperature range 795–1658 K by inverse drop calorimetric method by using a high-temperature differential calorimeter. Thermodynamic functions such as heat capacity, entropy, and Gibbs energy functions in the temperature range 298–1700 K were computed from the measured enthalpy increments.</abstract><cop>Dordrecht</cop><pub>Springer Netherlands</pub><doi>10.1007/s10973-017-6216-5</doi><tpages>10</tpages></addata></record> |
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| identifier | ISSN: 1388-6150 |
| ispartof | Journal of thermal analysis and calorimetry, 2017-09, Vol.129 (3), p.1563-1572 |
| issn | 1388-6150 1588-2926 |
| language | eng |
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| source | Springer Nature:Jisc Collections:Springer Nature Read and Publish 2023-2025: Springer Reading List |
| subjects | Analytical Chemistry Chemistry Chemistry and Materials Science Control rods Dysprosium Enthalpy Europium Gadolinium Heat measurement Inorganic Chemistry Materials selection Measurement Science and Instrumentation Nuclear energy Nuclear reactors Physical Chemistry Polymer Sciences Specific heat Titanates X-ray diffraction |
| title | High-temperature heat content and thermodynamic functions of REEuTi2O7 (RE = Gd, Dy) from calorimetric measurements |
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