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Thermophysical properties of N,N-dimеthylacetamide mixtures with n-butanol
The refraction, dielectric, viscosity, density, data of the binary mixtures of N , N -dimethylacetamide (DMA) with n -butanol at 308.15 and 313.15 K. The measured parameters used to obtain derived properties like Bruggeman factor, molar refraction and excess static dielectric constant, excess invers...
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| Published in: | Russian Journal of Physical Chemistry A 2017-09, Vol.91 (9), p.1710-1716 |
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| Main Authors: | , , , |
| Format: | Article |
| Language: | English |
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| cited_by | cdi_FETCH-LOGICAL-c2310-26d638fccc0ad64291df59fbd5da4c57a206820011f6003dc703d3101929bc9b3 |
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| cites | cdi_FETCH-LOGICAL-c2310-26d638fccc0ad64291df59fbd5da4c57a206820011f6003dc703d3101929bc9b3 |
| container_end_page | 1716 |
| container_issue | 9 |
| container_start_page | 1710 |
| container_title | Russian Journal of Physical Chemistry A |
| container_volume | 91 |
| creator | Maharolkar, Aruna P. Murugkar, A. G. Khirade, P. W. Mehrotra, S. C. |
| description | The refraction, dielectric, viscosity, density, data of the binary mixtures of
N
,
N
-dimethylacetamide (DMA) with
n
-butanol at 308.15 and 313.15 K. The measured parameters used to obtain derived properties like Bruggeman factor, molar refraction and excess static dielectric constant, excess inverse relaxation time, excess molar volume and excess viscosity, excess molar refraction. The variation in magnitude with composition and temperature of these quantities has been used to discuss the type, strength and nature of binary interactions. Results confirm that there are strong hydrogen-bond interactions between unlike molecules of DMA+
n
-butanol mixtures and that 1: 1 complexes are formed and strength of intermolecular interaction increases with temperature. |
| doi_str_mv | 10.1134/S0036024417090060 |
| format | article |
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N
,
N
-dimethylacetamide (DMA) with
n
-butanol at 308.15 and 313.15 K. The measured parameters used to obtain derived properties like Bruggeman factor, molar refraction and excess static dielectric constant, excess inverse relaxation time, excess molar volume and excess viscosity, excess molar refraction. The variation in magnitude with composition and temperature of these quantities has been used to discuss the type, strength and nature of binary interactions. Results confirm that there are strong hydrogen-bond interactions between unlike molecules of DMA+
n
-butanol mixtures and that 1: 1 complexes are formed and strength of intermolecular interaction increases with temperature.</description><identifier>ISSN: 0036-0244</identifier><identifier>EISSN: 1531-863X</identifier><identifier>DOI: 10.1134/S0036024417090060</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Binary mixtures ; Butanol ; Chemistry ; Chemistry and Materials Science ; Dielectric properties ; Dielectric relaxation ; Molar volume ; Physical Chemistry ; Physical Chemistry of Solutions ; Refraction ; Relaxation time ; Thermophysical properties ; Viscosity</subject><ispartof>Russian Journal of Physical Chemistry A, 2017-09, Vol.91 (9), p.1710-1716</ispartof><rights>Pleiades Publishing, Ltd. 2017</rights><rights>Copyright Springer Science & Business Media 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2310-26d638fccc0ad64291df59fbd5da4c57a206820011f6003dc703d3101929bc9b3</citedby><cites>FETCH-LOGICAL-c2310-26d638fccc0ad64291df59fbd5da4c57a206820011f6003dc703d3101929bc9b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Maharolkar, Aruna P.</creatorcontrib><creatorcontrib>Murugkar, A. G.</creatorcontrib><creatorcontrib>Khirade, P. W.</creatorcontrib><creatorcontrib>Mehrotra, S. C.</creatorcontrib><title>Thermophysical properties of N,N-dimеthylacetamide mixtures with n-butanol</title><title>Russian Journal of Physical Chemistry A</title><addtitle>Russ. J. Phys. Chem</addtitle><description>The refraction, dielectric, viscosity, density, data of the binary mixtures of
N
,
N
-dimethylacetamide (DMA) with
n
-butanol at 308.15 and 313.15 K. The measured parameters used to obtain derived properties like Bruggeman factor, molar refraction and excess static dielectric constant, excess inverse relaxation time, excess molar volume and excess viscosity, excess molar refraction. The variation in magnitude with composition and temperature of these quantities has been used to discuss the type, strength and nature of binary interactions. Results confirm that there are strong hydrogen-bond interactions between unlike molecules of DMA+
n
-butanol mixtures and that 1: 1 complexes are formed and strength of intermolecular interaction increases with temperature.</description><subject>Binary mixtures</subject><subject>Butanol</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Dielectric properties</subject><subject>Dielectric relaxation</subject><subject>Molar volume</subject><subject>Physical Chemistry</subject><subject>Physical Chemistry of Solutions</subject><subject>Refraction</subject><subject>Relaxation time</subject><subject>Thermophysical properties</subject><subject>Viscosity</subject><issn>0036-0244</issn><issn>1531-863X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp1kE1OwzAQhS0EEqVwAHaR2BKYsR2nWaKKP1GVBUViFzm2Q1LlD9sR9GDcgyPhqiyQEJuZxXzvzdMj5BThApHxyycAJoByjilkAAL2yAQThvFMsJd9Mtme4-39kBw5twbgAeUT8rCqjG37odq4WskmGmw_GOtr46K-jJbny1jX7denrzaNVMbLttYmausPP9qAvNe-irq4GL3s-uaYHJSycebkZ0_J8831an4XLx5v7-dXi1hRhhBToQWblUopkFpwmqEuk6wsdKIlV0kqKYgZBUAsRYitVRpGEGJGs0JlBZuSs51vCPs2GufzdT_aLrzMMWOYcipEEijcUcr2zllT5oOtW2k3OUK-7Sz_01nQ0J3GBbZ7NfaX87-ib0q4be4</recordid><startdate>20170901</startdate><enddate>20170901</enddate><creator>Maharolkar, Aruna P.</creator><creator>Murugkar, A. G.</creator><creator>Khirade, P. W.</creator><creator>Mehrotra, S. C.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20170901</creationdate><title>Thermophysical properties of N,N-dimеthylacetamide mixtures with n-butanol</title><author>Maharolkar, Aruna P. ; Murugkar, A. G. ; Khirade, P. W. ; Mehrotra, S. C.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2310-26d638fccc0ad64291df59fbd5da4c57a206820011f6003dc703d3101929bc9b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Binary mixtures</topic><topic>Butanol</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Dielectric properties</topic><topic>Dielectric relaxation</topic><topic>Molar volume</topic><topic>Physical Chemistry</topic><topic>Physical Chemistry of Solutions</topic><topic>Refraction</topic><topic>Relaxation time</topic><topic>Thermophysical properties</topic><topic>Viscosity</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maharolkar, Aruna P.</creatorcontrib><creatorcontrib>Murugkar, A. G.</creatorcontrib><creatorcontrib>Khirade, P. W.</creatorcontrib><creatorcontrib>Mehrotra, S. C.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian Journal of Physical Chemistry A</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maharolkar, Aruna P.</au><au>Murugkar, A. G.</au><au>Khirade, P. W.</au><au>Mehrotra, S. C.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermophysical properties of N,N-dimеthylacetamide mixtures with n-butanol</atitle><jtitle>Russian Journal of Physical Chemistry A</jtitle><stitle>Russ. J. Phys. Chem</stitle><date>2017-09-01</date><risdate>2017</risdate><volume>91</volume><issue>9</issue><spage>1710</spage><epage>1716</epage><pages>1710-1716</pages><issn>0036-0244</issn><eissn>1531-863X</eissn><abstract>The refraction, dielectric, viscosity, density, data of the binary mixtures of
N
,
N
-dimethylacetamide (DMA) with
n
-butanol at 308.15 and 313.15 K. The measured parameters used to obtain derived properties like Bruggeman factor, molar refraction and excess static dielectric constant, excess inverse relaxation time, excess molar volume and excess viscosity, excess molar refraction. The variation in magnitude with composition and temperature of these quantities has been used to discuss the type, strength and nature of binary interactions. Results confirm that there are strong hydrogen-bond interactions between unlike molecules of DMA+
n
-butanol mixtures and that 1: 1 complexes are formed and strength of intermolecular interaction increases with temperature.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0036024417090060</doi><tpages>7</tpages></addata></record> |
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| identifier | ISSN: 0036-0244 |
| ispartof | Russian Journal of Physical Chemistry A, 2017-09, Vol.91 (9), p.1710-1716 |
| issn | 0036-0244 1531-863X |
| language | eng |
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| source | Springer Link |
| subjects | Binary mixtures Butanol Chemistry Chemistry and Materials Science Dielectric properties Dielectric relaxation Molar volume Physical Chemistry Physical Chemistry of Solutions Refraction Relaxation time Thermophysical properties Viscosity |
| title | Thermophysical properties of N,N-dimеthylacetamide mixtures with n-butanol |
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