Water-soluble inorganic photocatalyst for overall water splitting

• Published in: Applied catalysis. B, Environmental Environmental, 2017-07, Vol.209, p.247-252
• Main Authors: Li, Yu Hang, Wang, Yun, Zheng, Li Rong, Zhao, Hui Jun, Yang, Hua Gui, Li, Chunzhong
• Format: Article
• Language: English
• Subjects: Catalysis; Chemical compounds; Electromagnetic absorption; Electronics industry; Hybrids; Illumination; Irradiation; Light emitting diodes; Molybdate; Organic light emitting diodes; Overall water splitting; Oxidation; Photocatalysis; Photocatalysts; Photosynthesis; Photovoltaic cells; Photovoltaics; Radiation; Salts; Semiconductors; Sodium; Sodium molybdate; Sodium molybdate salt; Solar cells; Splitting; Studies; Water splitting; Water-soluble inorganics
• ISSN: 0926-3373; 1873-3883
• DOI: 10.1016/j.apcatb.2017.03.001

[Display omitted] •Water-soluble Na2MoO4 salt demonstrates its capacity for photocatalytic overall water splitting.•Water-soluble inorganics has the capacity for photocatalytic overall water splitting.•Water-soluble Na2MoO4 can act as a new type of photocatalyst for overall water splitting.•Water-soluble semiconductors may have great potential to be applied in numerous important applications such as catalysis, photovoltaics, light emitting diodes and artificial photosynthesis. In the past 45 years, the search for semiconductors as active photocatalysts for overall water splitting has focused on insoluble materials and their hybrids. An important question is whether soluble semiconductors have the capacity for photocatalysis or similar applications. The dissolved semiconductors will lose the energy band structures for light absorption; however, the undissolved part in saturated solution can still generate electrons and holes under illumination. Unfortunately, this possibility has never been realized. Here we clearly demonstrate the use of a water-soluble sodium molybdate salt as an effective photocatalyst. The material can photocatalyze simultaneously the oxidation and reduction of water under band-gap irradiation. We anticipate that, as a large and traditional class of chemical compounds, the soluble semiconductors may have great potential to be applied in numerous important applications such as catalysis, photovoltaics, light emitting diodes and artificial photosynthesis.