Thin-film nanocomposites of BDD/CNT deposited on carbon fiber

• Published in: Diamond and related materials 2017-05, Vol.75, p.116-122
• Main Authors: Silva, Amanda Araujo, Pinheiro, Romário Araújo, Razzino, Cláudia do Amaral, Trava-Airoldi, Vladimir Jesus, Corat, Evaldo José
• Format: Article
• Language: English
• Subjects: Boron fibers; Camphor; Capacitance; Carbon fiber; Carbon fibers; Carbon nanotubes; Catalysts; Chemical vapor deposition; Coated electrodes; CVD method; Diamonds; Dip coatings; Electrochemical analysis; Electrochemical impedance spectroscopy; Electrochemistry; Emission spectroscopy; Field emission; Functionalized; Immersion coating; Metal particles; Nanocomposite; Nanocomposites; Oxygen plasma; Particle physics; Porous doped diamond; Raman spectroscopy; Scanning electron microscopy; Thin films
• ISSN: 0925-9635; 1879-0062
• DOI: 10.1016/j.diamond.2017.02.017

The nanocomposites of porous boron-doped diamond deposited on carbon nanotubes (BDD/CNTs) present great surface area and high capacitance, making them a material of considerable interest for application in electrochemistry. In this work, we present a new approach in which this nanocomposite is deposited on carbon fiber (CF) to increase the surface area and the capacitance comparing to the unsized CF electrode. We performed the dip-coating for catalyst deposition on CF surface. After, CNTs growth followed in a tubular reactor at 650°C for 20min, using camphor in a 200g/L hexane solution as the carbon source. Electrostatic Self Assembly (ESA) seeding of nanodiamond (ND) went on by grafting polar groups onto CNTs surface by oxygen plasma functionalization. The seeding process was made with 4nm diamond nanoparticles dispersed in KCl aqueous solution. The BDD films were deposited by Hot Filament Chemical Vapor Deposition (HFCVD) reactor. The authors studied the composites morphology, structure and electrochemical properties by Scanning Electron Microscopy with Field Emission Gun (FEG-SEM), Raman spectroscopy, cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). This new material presented larger surface area and higher capacitance compared to CF without treatment, as presented in electrochemical analysis results. The SEM micrographs showed absence of metallic particles on CNTs structure, what promoted a better quality diamond growth. •This obtainment method promoted an increase in carbon fiber capacitance of around 13 times.•The composite electrodes combined electrochemical properties with capacitive behavior.•Flexible and tridimensional electrodes had been produced by the BDD/CNT nanocomposite deposition on carbon fiber. [Display omitted]