Effects of Zn concentration and heat treatment on the microstructure, mechanical properties and corrosion behavior of as-extruded Mg-Zn alloys produced by powder metallurgy

• Published in: Journal of alloys and compounds 2017-02, Vol.693, p.1277-1289
• Main Authors: Yan, Yang, Cao, Hanwen, Kang, Yijun, Yu, Kun, Xiao, Tao, Luo, Jie, Deng, Youwen, Fang, Hongjie, Xiong, Hanqing, Dai, Yilong
• Format: Article
• Language: English
• Subjects: Alloy development; Alloy powders; Biocompatibility; Biodegradability; Biomedical materials; Compression tests; Corrosion behavior; Corrosion currents; Corrosion potential; Corrosion products; Corrosion resistant alloys; Cytocompatibility; Extrusion; Galvanic corrosion; Heat treatment; Immersion tests (corrosion); Intermetallic phases; Magnesium; Magnesium alloy; Magnesium base alloys; Mechanical properties; Metallurgical analysis; Microstructure; Pitting (corrosion); Powder metallurgy; Surgical implants; Toxicity; Zinc base alloys
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2016.10.017

Magnesium alloys have been regarded as potential degradable biomedical materials due to their suitable mechanical properties and excellent biocompatibility. In this study, Mg-Zn alloys were fabricated by powder metallurgy and then hot extruded. The effects of Zn concentration and heat treatment on their microstructure, mechanical properties and corrosion behavior were investigated. The compression test results showed that their mechanical properties were suitable for bone tissue engineering. The corrosion behavior of Mg-Zn alloys was analyzed by immersion tests and electrochemical tests in Ringer's solution. The results revealed that the increasing Zn concentration reduced the corrosion potential but increased corrosion current because severe micro-galvanic corrosion was caused by more large-size intermetallic phases. Although solid solution treatment could reduce intermetallic phase amounts, it caused micropores on the surface. And these micropores could resulted in the pitting corrosion and reduce the corrosion resistance. Notably, aging treatment could reduce the segregation of Zn and promote the compactness and uniformity of corrosion product layer on the surface, leading to the improvement of corrosion resistance. In addition, the as-extruded Mg-6%Zn alloy (wt.%) aged for 72 h was harmless to L-929 cells in cytotoxicity test. Consequently, the as-extruded Mg-Zn alloys prepared by powder metallurgy are promising to develop to be ideal biodegradable implants for bone tissue engineering. •The Mg-Zn alloys are prepared by powder metallurgy and then hot extruded.•The effects of Zn concentration and heat treatment on properties are investigated.•The Mg-Zn intermetallic phases are characterized and studied in detail.•The mechanical properties of the Mg-Zn alloys are suitable for bone implants.•The Mg-6%Zn alloy imparted by aging treatment shows the best corrosion resistance.