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Influence of operating conditions and wastewater-specific parameters on the electrochemical bulk disinfection of biologically treated sewage at boron-doped diamond (BDD) electrodes

The aim of this study was to investigate an electrochemical process for bulk disinfection of biologically treated sewage. The influence of operating conditions (current density and flow rate) on the electrochemical formation of free chlorine in the sewage was determined. Furthermore, the effect of w...

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Bibliographic Details
Published in:Desalination and water treatment 2012-08, Vol.46 (1-3), p.160-167
Main Authors: Haaken, Daniela, Dittmar, Thomas, Schmalz, Viktor, Worch, Eckhard
Format: Article
Language:English
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Summary:The aim of this study was to investigate an electrochemical process for bulk disinfection of biologically treated sewage. The influence of operating conditions (current density and flow rate) on the electrochemical formation of free chlorine in the sewage was determined. Furthermore, the effect of wastewater-specific parameters on the inactivation of Escherichia coli was studied. The disinfection capacity is primarily influenced by the concentration of electrochemically produced free chlorine. The production rate of free chlorine is independent of the flow rate within the range of 25–125 L h-1. The investigations have also shown that the electrochemical disinfection of E. coli in secondary effluents with BDD electrodes proceeds effectively at an electric charge input of 0.1–0.15 Ah L-1 corresponding to an energy expenditure of 2.0–2.6 kWh m-3. The electrochemically generated concentration of free chlorine (c = 0.4–0.6 mg L-1) is sufficient for an E. coli reduction of four log levels under the following conditions: after-reaction time of 15–20 min, T > 6°C, pH 
ISSN:1944-3986
1944-3994
1944-3986
DOI:10.1080/19443994.2012.677523