Enhanced Luminescence of La3+-Doped Gadolinium Oxysulfide with Tunable Crystalline Size

• Published in: Journal of electronic materials 2017-10, Vol.46 (10), p.5986-5994
• Main Authors: Ding, Yu-Jie, Wang, Li-Xi, Zhang, Qi-Tu, Pan, Shi-Bing
• Format: Article
• Language: English
• Subjects: Band theory; Characterization and Evaluation of Materials; Chemistry and Materials Science; Conduction bands; Crystal structure; Deformation; Electron density; Electronics and Microelectronics; Energy gap; Excitation spectra; Gadolinium; Instrumentation; Luminescence; Materials Science; Optical and Electronic Materials; Optical properties; Particle size; Phosphors; Solid State Physics
• ISSN: 0361-5235; 1543-186X
• DOI: 10.1007/s11664-017-5570-1

The concentration of La 3+ in (La x Gd 1− x ) 2 O 2 S:Tb phosphors prepared by the sulfide fusion method from coprecipitated oxalate precursors has been tuned, and the prominent effect on the crystalline size, particle size, and luminescence properties investigated. First-principles calculations were used to characterize the charge deformation, energy gap, and crystal field. According to density functional theory, the electron density of states in conduction bands increased with increase in the La 3+ concentration. The increased electronic density strengthened the repulsion and thus decreased the diffusion so as to decrease the crystalline size from 106.2 nm to 37.3 nm. The particle size of (La x Gd 1− x ) 2 O 2 S:Tb increased from 0.21  μ m to 1.25  μ m as the La 3+ concentration was increased from 15 mol.% to 60 mol.%. The excitation spectrum shifted towards shorter wavelength, enhancing the luminescence intensity of (La x Gd 1− x ) 2 O 2 S:Tb when excited at 254 nm. Furthermore, shorter lifetime was obtained due to lower symmetry as more Gd 3+ was substituted by La 3+ ions.