Kinetics and mechanism of radiation telomerization of tetrafluoroethylene in hexafluoropropan-2-ol and trifluoroethanol

The kinetics of radiation telomerization of tetrafluoroethylene (TFE) in trifluoroethanol and hexafluoropropan-2-ol (HFIP) has been investigated by method of kinetic calorimetry. The nature of active centers initiating the process of telomerization of tetrafluoroethylene in hexafluoroisopropanol in...

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Bibliographic Details
Published in:Russian chemical bulletin 2017-03, Vol.66 (3), p.468-473
Main Authors: Kichigina, G. A., Kushch, P. P., Kiryukhin, D. P., Kuzina, S. I., Mikhailov, A. I.
Format: Article
Language:English
Subjects:
Chemistry
Chemistry and Materials Science
Chemistry/Food Science
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Heat measurement
Infrared spectroscopy
Inorganic Chemistry
Molecular structure
Organic Chemistry
Spectroscopic analysis
Spectrum analysis
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Summary:The kinetics of radiation telomerization of tetrafluoroethylene (TFE) in trifluoroethanol and hexafluoropropan-2-ol (HFIP) has been investigated by method of kinetic calorimetry. The nature of active centers initiating the process of telomerization of tetrafluoroethylene in hexafluoroisopropanol in the temperature range of 77—300 K was investigated by ESR spectroscopy. The molecular structure and properties of the obtained telomeres were studied by IR spectroscopy and TGA.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-017-1756-1