Synthesis and characterization of novel polymeric organic–inorganic complex framework based on sodium 2,4-dioxo-6-aryl-3-oxa-bicyclo[3.1.0]hexane-1,5-dicarboxylate (SDAOBDC) with three-dimensional hybrid networks

Synthesis and characterization of novel polymeric organic–inorganic complex based on sodium 2,4-dioxo-6-aryl-3-oxa-bicyclo[3,1,0]hexane-1,5-dicarboxylate with three-dimensional hybrid networks were reported. The polymeric complex was crystallizing in the triclinic, space group P1 . As determined by...

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Bibliographic Details
Published in:Journal of the Iranian Chemical Society 2017-10, Vol.14 (10), p.2143-2156
Main Authors: Kashani, Elmira, Noroozi Pesyan, Nader, Rashidnejad, Hamid, Poursattar Marjani, Ahmad, Yaghoobnejad Asl, Hooman
Format: Article
Language:English
Subjects:
Analytical Chemistry
Aromatic compounds
Biochemistry
Carbonyls
Chemical synthesis
Chemistry
Chemistry and Materials Science
Crystal structure
Crystallography
Flame photometry
Infrared spectroscopy
Inorganic Chemistry
Molecular structure
NMR
Nuclear magnetic resonance
Organic Chemistry
Original Paper
Oxygen
Photometry
Physical Chemistry
Single crystals
Sodium
Structural analysis
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Summary:Synthesis and characterization of novel polymeric organic–inorganic complex based on sodium 2,4-dioxo-6-aryl-3-oxa-bicyclo[3,1,0]hexane-1,5-dicarboxylate with three-dimensional hybrid networks were reported. The polymeric complex was crystallizing in the triclinic, space group P1 . As determined by X-ray single-crystal analysis, in this compound each Na ion is coordinated by six O atoms: two from different carbonyl oxygen atom of carboxylic acid groups, two from bridged carbonyl oxygen atom of carboxylic acid groups, one from the carbonyl oxygen atom of cyclic anhydride and one from water molecule. The structure characterization was done by means of IR, 1 H, 13 C NMR, UV–Vis spectroscopies, Tg, flame photometry and X-ray crystallographic analysis.
ISSN:1735-207X
1735-2428
DOI:10.1007/s13738-017-1151-8