Detailed study of structural and luminescent properties of Y2-xEuxZr2O7 (0 ≤ x ≤ 1) nanophosphors

• Published in: Journal of alloys and compounds 2017-07, Vol.712, p.437-444
• Main Authors: Papan, Jelena, Vuković, Katarina, Ahrenkiel, Scott P., Jovanović, Dragana J., Dramićanin, Miroslav D.
• Format: Article
• Language: English
• Subjects: Combustion synthesis; Diffraction; Emission analysis; Emission quenching; Europium(III); Fluorite; High resolution; Judd-Ofelt analysis; Lanthanide luminescence; Luminescence; Luminescence quenching; Mathematical analysis; Nanocrystals; Nanophosphors; Optical properties; Particle decay; Particle physics; Phosphors; Quadrupole interaction; Quadrupoles; Quantum dots; Quantum efficiency; Quenching; Studies; Transmission electron microscopy; Y2Zr2O7
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2017.04.139

Nanocrystalline Y2-xEuxZr2O7 (0 ≤ x ≤ 1) phosphor particles were prepared by polymer facilitated combustion and subsequent calcination at 800 °C. The thorough study of Eu-concentration influence on particle's structure, morphology and luminescence is presented. This type of synthesis provides particles of ∼5 nm in diameter, which crystallize in a defect fluorite structure (space group Fm-3m), and where each particle consists of a single crystallite, as revealed by X-ray diffraction and high-resolution transmission electron microscopy. With the increase of Eu concentration, the unit-cell parameter slightly increases to accommodate larger Eu3+ ions at sites of smaller Y3+, while the shape and size of particles remain the same. Analysis of emission intensity and decay dependence on Eu concentration showed that this host material could be heavily doped with Eu since concentration quenching of emission occurs at high Eu content of 25–30 at.% (with respect to Y ions). The critical distance for energy transfer between Eu ions is estimated to 10.28 Å and dipole–quadrupole interaction is found as the dominant mechanism responsible for the concentration quenching of emission. Radiative and non-radiative transition rates, the quantum efficiency of emission, Ω-intensity parameters, and branching ratios of Eu3+ emission are calculated for nanocrystals of all doping concentrations. It is found that more “to-the-point” expression 86% of emission comes from 5D0 → 7F2 and 5D0 → 7F1 transitions. Therefore, this phosphor emits pure red light with (0.661, 0.338) CIE color coordinates. [Display omitted] •Y2Zr2O7:Eu3+ nanocrystals were prepared by polymer facilitated combustion method.•Concentration quenching of emission occurs at high Eu content of 25–30 at.%.•Majority of emission comes from 5D0 → 7F2 and 5D0 → 7F1 transitions (∼86%)•Y2Zr2O7:Eu3+ nanocrystals emit pure red light with (0.661, 0.338) CIE coordinates.