Chemistry of (dinitromethyl)azines

This review covers the methods applicable for the synthesis of (dinitromethyl)azines: nitration of azine derivatives, azine ring formation,nucleophilic su bstitution in azine rings by the action of dinitrocarbanions, and denitration of trinitromethylazines. Further reactions with the conservation of...

Full description

Saved in:
Bibliographic Details
Published in:Chemistry of heterocyclic compounds (New York, N.Y. 1965) N.Y. 1965), 2017-06, Vol.53 (6-7), p.659-669
Main Authors: Bakharev, Vladimir V., Gidaspov, Alexander A., Parfenov, Victor E.
Format: Article
Language:English
Subjects:
Azines
Chemistry
Chemistry and Materials Science
Denitration
Energetic materials
Functional groups
Nitration
Organic Chemistry
Pharmacy
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:This review covers the methods applicable for the synthesis of (dinitromethyl)azines: nitration of azine derivatives, azine ring formation,nucleophilic su bstitution in azine rings by the action of dinitrocarbanions, and denitration of trinitromethylazines. Further reactions with the conservation of dinitromethyl group, as well as its transformations into other functional groups, or modification of other substituents in (dinitromethyl)azines are also considered. Dinitromethylazines are of interest as energetic materials with low sensitivity and as biologically active compounds.
ISSN:0009-3122
1573-8353
DOI:10.1007/s10593-017-2107-8