Plasmon-enhanced fluorescence of CaF2:Eu2+ nanocrystals by Ag nanoparticles

• Published in: Journal of alloys and compounds 2017-09, Vol.719, p.159-170
• Main Authors: Ye, Weihao, Huang, Qiying, Jiao, Xianfu, Liu, Xiaotang, Hu, Guangqi
• Format: Article
• Language: English
• Subjects: Absorption spectra; Ag nanoparticles; Calcium fluoride; Chemical compounds; Construction materials; Europium; Fluorescence; Nanocrystals; Nanoparticles; Photoluminescence; Silver; Surface plasmon; Transmission electron microscopy; X-ray diffraction
• ISSN: 0925-8388; 1873-4669
• DOI: 10.1016/j.jallcom.2017.05.181

We report plasmon-enhanced fluorescence in Eu2+ doped CaF2 (CaF2:Eu2+) nanocrystals assembled with Ag nanoparticles (NPs) using a simple hydrothermal method. The structure, morphology and composition of the nanocrystals are confirmed by X-ray diffraction (XRD), transmission electron Microscopy (TEM), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), and UV–vis absorption spectrum. Ag nanoparticles are ideal building blocks for plasmonic materials that can exhibit a wide range of unique and potentially useful optical phenomena. Surface plasmon enhancement makes significant contribution to enhance the blue fluorescence emission of CaF2:Eu2+. The enhancement on the Eu emission in visible regions is up to a factor of 12.3-fold. As shown in time-resolved measurements, surface Plasmon Resonance (SPR) can reduce the fluorescence lifetime and increase the quantum yield. Furthermore, with increasing Ag concentration, the fluorescence intensity increases to its maximum and then decreases. •CaF2: Eu2+ nanocrystals assembled with Ag NPs using a simple hydrothermal method.•Surface Plasmon enhancement on the Eu emission is up to a factor of 12.3-fold.•The fluorescence intensity is enhanced with increasing amount of Cit-Ag NPs.•Based on the EPR result, the reduction of Eu3+→Eu2+ has occurred by Cit-Ag catalyst.•SPR results in an increase in the quantum yield and a decrease in the lifetime.