Sunlight-induced decarboxylative radical addition of carboxylic acids to electron-deficient alkenes using a millitube reactor

[Display omitted] •Use of FEP millitube reactor significantly improved the efficiency of photoreactions.•Sunlight-induced photoreaction is achieved using FEP millitube reactor.•This method generates alkyl radicals from carboxylic acids under mild conditions. The use of a fluorinated ethylene propyle...

Full description

Saved in:
Bibliographic Details
Published in:Journal of photochemistry and photobiology. A, Chemistry. Chemistry., 2016-12, Vol.331, p.17-21
Main Authors: Yoshimi, Yasuharu, Nishio, Akinori, Hayashi, Masae, Morita, Toshio
Format: Article
Language:English
Subjects:
Aliphatic compounds
Alkenes
Amino acids
Carboxylic acids
Decarboxylative radical addition
Electron-deficient alkene
Ethylene
Fluorinated ethylene propylenes
Millitube reactor
Photochemistry
Reactors
Sun
Sunlight
Sunlight-induced
Ultraviolet radiation
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:[Display omitted] •Use of FEP millitube reactor significantly improved the efficiency of photoreactions.•Sunlight-induced photoreaction is achieved using FEP millitube reactor.•This method generates alkyl radicals from carboxylic acids under mild conditions. The use of a fluorinated ethylene propylene (FEP) millitube reactor significantly improved the efficiency of the photoinduced decarboxylative radical addition of aliphatic carboxylic acids to electron-deficient alkenes, producing the corresponding γ-amino acid derivative and macrocyclic lactone. These sunlight-induced photoreactions were achieved using a millitube reactor, even though the photosensitizer used in this system absorbs only UV light.
ISSN:1010-6030
1873-2666
DOI:10.1016/j.jphotochem.2016.03.012