Structure of a new chelate complex MO2O3(dpm)4

A new Mo 2 O 3 (dpm) 4 compound ( I ) is synthesized by the interaction of Mo(CO) 6 with 2,2,6,6-tetramethylheptanedione-3,5 (dpm). The structure of complex I determined by the XRD method is as follows: triclinic crystal system, space group P –1, a = 10.1780(7) Å, b = 10.1817(6) Å, c = 13.3255(9) Å,...

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Bibliographic Details
Published in:Journal of structural chemistry 2017-07, Vol.58 (4), p.758-762
Main Authors: Ledneva, A. Yu, Artemkina, S. B., Stabnikov, P. A., Yanshole, L. V., Fedorov, V. E.
Format: Article
Language:English
Subjects:
Atomic
Atomic/Molecular Structure and Spectra
Chemistry
Chemistry and Materials Science
Coordination compounds
Infrared spectroscopy
Inorganic Chemistry
Molecular
Optical and Plasma Physics
Physical Chemistry
Solid State Physics
Spectrometry
Thermogravimetric analysis
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Summary:A new Mo 2 O 3 (dpm) 4 compound ( I ) is synthesized by the interaction of Mo(CO) 6 with 2,2,6,6-tetramethylheptanedione-3,5 (dpm). The structure of complex I determined by the XRD method is as follows: triclinic crystal system, space group P –1, a = 10.1780(7) Å, b = 10.1817(6) Å, c = 13.3255(9) Å, α = 110.562(2)°, β = 102.233(2)°, γ = 93.9041(19)°, V = 1248.17(14) Å 3 . The compound is characterized by IR spectroscopy, mass-spectrometry and thermogravimetric analysis (TGA).
ISSN:0022-4766
1573-8779
DOI:10.1134/S0022476617040163