Corrosion protection of AISI 1018 steel using Co-doped TiO2/polypyrrole nanocomposites in 3.5% NaCl solution

• Published in: Materials chemistry and physics 2017-05, Vol.192, p.361-373
• Main Authors: Ladan, Magaji, Basirun, Wan Jeffrey, Kazi, Salim Newaz, Rahman, Fariza Abdul
• Format: Article
• Language: English
• Subjects: Butvar; Co-doped TiO2; Corrosion; Corrosion prevention; Corrosion resistant steels; EIS; Electrochemical impedance spectroscopy; Field emission microscopy; Nanocomposites; Nanoparticles; Open circuit voltage; Polarization; Polymerization; Polypyrrole; Protective coatings; Sodium chloride; Steel; Studies; Synthesis; Titanium dioxide; Titanium oxide powders; Titanium oxides; Transmission electron microscopy
• ISSN: 0254-0584; 1879-3312
• DOI: 10.1016/j.matchemphys.2017.01.085

A polypyrrole nanocomposites (PPy NTCs) have been effectively synthesized in the presence of TiO2 and Co-doped TiO2 nanoparticles (NPs) by an in situ chemical oxidative polymerization. Field Emission Scanning Electron Microscopy and Transmission Electron Microscopy revealed a tube shape structure of the PPy. The TEM results confirmed that the nanocomposite size of Co-doped TiO2/PPy NTCs was smaller than TiO2/PPy NTCs thereby increasing the interaction between the PPy nanotube and the AISI steel surface. The corrosion performance of the coatings was evaluated by electrochemical impedance spectroscopy (EIS) and potentiodynamic polarization measurements in 3.5% NaCl solution. The EIS results show that the log |Z| of AISI 1018 coated with Co-doped TiO2/PPy NTCs and TiO2/PPy NTCs reached about 8.2 and 6.0 respectively after 30 days of exposure in 3.5% NaCl solution. This is likely due to the increased surface area of the PPy synthesized in the presence of Co-doped TiO2 NPs. The EIS results are confirmed by the potentiodynamic polarization and open circuit potential values of the Co-doped TiO2/PPy which indicated little changes between 1 and 30 days of exposure which confirms the protection ability of this coating. . It is evident that the presence of Co-doped TiO2 NPs can enhance the resistance against corrosion at the steel/electrolyte interface. [Display omitted] •Polymerization of pyrrole monomer in the presence of Co-doped TiO2 decreases the size of the polypyrrole nanotube (PPy NT).•The corrosion protection increases with the increase in PPy NT dispersion.•The corrosion resistance of steel coated with Co-doped TiO2/PPy NTCs is considerably higher.•TiO2/PPy with Co doping reduces the charge transfer across the electrolyte/AISI 1018 steel interface.