The Effect of Ultrasonic Melt Treatment on Macro-Segregation and Peritectic Transformation in an Al-19Si-4Fe Alloy

• Published in: Metallurgical and materials transactions. A, Physical metallurgy and materials science Physical metallurgy and materials science, 2017-11, Vol.48 (11), p.5579-5590
• Main Authors: Todaro, C. J., Easton, M. A., Qiu, D., Wang, G., StJohn, D. H., Qian, M.
• Format: Article
• Language: English
• Subjects: Aluminum base alloys; Characterization and Evaluation of Materials; Chemistry and Materials Science; Constitution; Eutectics; Ferrous alloys; Intermetallic compounds; Materials Science; Metallic Materials; Metallography; Metallurgy; Microstructure; Nanotechnology; Particle size distribution; Structural Materials; Surfaces and Interfaces; Thin Films; Transformations
• ISSN: 1073-5623; 1543-1940
• DOI: 10.1007/s11661-017-4325-1

It is well documented that ultrasonic melt treatment (USMT) can refine dendritic and eutectic microstructures during solidification, but much less attention has been paid to the effect of USMT on macro-segregation and intermetallic transformations. In this research, macro-segregation and primary Fe-containing intermetallic peritectic transformations in an Al-19 wt pct Si-4 wt pct Fe alloy were investigated without and with USMT. Macrostructural examination showed that in the absence of USMT the ingot revealed considerable non-uniform distribution of both the primary Fe-containing intermetallic and primary Si particles, whereas the ingot with USMT exhibited near homogeneous distribution of both primary phases, i.e., reduced macro-segregation. The beneficial effect of USMT on relieving macro-segregation was further examined using quantitative microstructural metallography and the results indicated that the area fraction, number density, and size distribution of both primary phases became essentially uniform across the ingot after USMT. USMT further exerted a significant impact on the constitution of the primary Fe-containing intermetallics, where complex particles of δ-Al 3 FeSi 2 /β-Al 5 FeSi were prominent without USMT, while few δ-Al 3 FeSi 2 particles were observed after USMT and the primary Fe-containing intermetallics existed mostly as the single-phase β-Al 5 FeSi. The underlying reason was attributed to the reduction in the size of the primary δ-Al 3 FeSi 2 particles which ensures the complete transformation of most primary δ-Al 3 FeSi 2 particles to the peritectic β-Al 5 FeSi phase.